Coating Steel with Nickel by Immersion in Nickel Chloride Solutions

Wesley, W. A.; Copson, H. R.

doi:10.1149/1.2773820

Cited by 8 publications

(4 citation statements)

References 2 publications

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“…Nickel can be deposited via conventional EL ( vide infra ) and galvanic ,,,− methods, though in the latter case Ni more often functions as a sacrificial substrate for replacement by other metals than the deposited metal. ,,,,− Conventional EL Ni depositions utilize baths containing H 2 PO 2 – , − amine boranes, ,− BH 4 – , − or to a lesser extent, N 2 H 4 , − as reducing agents. Baths containing H 2 PO 2 – deposit the metal as NiP alloys, whereas those containing amine boranes or BH 4 – yield NiB alloys and those containing N 2 H 4 deposit Ni metal.…”

Section: Elementsmentioning

confidence: 99%

“…However, it is the discovery of hypophosphite (H 2 PO 2 – ) as a reducing agent for Cu II and Ni II salts in the 19th century, together with the characterization of the reduction process and its extension to include other metal salts during the early 20th century, − that have provided the background for growth of the field. The pivotal demonstration by Brenner and Rendell, who coined the term “electroless”, of EL Ni metal plating of steel , is largely responsible for igniting increased interest in practical applications of the EL process − that mark the modern era for its widescale adoption and exploitation in industry.…”

Section: Introductionmentioning

confidence: 99%

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Electroless Metallization of the Elements: Survey and Progress

Turró

Dressick

2022

ACS Appl. Electron. Mater.

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The electroless plating of metals and their alloys, oxides, and chalcogenides represents a critically important technology for the automotive, aerospace, machine tools, and, especially, the electronics industries. Since the initial efforts involving the plating of industrially important metals, such as Ni, Co, Cu, Ag, and Au, in the mid-20th century, the process has evolved to encompass a growing number of elements. At the same time, this expansion in the palette of accessible metals has enabled progress in these industries and evoked new nonconventional applications. In this review, we collect and survey available electroless processes in aqueous and organic solvent systems for each element organized according to position in the Periodic Table as a resource for the reader. Examples illustrating progress in the field are presented and are described in sufficient detail to be useful and understandable for both the expert and nonexpert. Given the historical importance of electronics as a driver for development of electroless processes, examples are electronics-related where possible. However, we strive to also include examples of applications in nontraditional fields to provide the reader with a sense of generality available for electroless methods. The review closes with an outlook for the field and a challenge to scientists and engineers to adapt electroless processes for new applications to continue the growth of the field.

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Section: Elementsmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Electroless Metallization of the Elements: Survey and Progress

Turró

Dressick

2022

ACS Appl. Electron. Mater.

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“…Under favorable conditions it is possible to deposit an immersion coating of nickel on steel from a hot concentrated solution of nickel chloride of 0.00002-inch thickness in 10 minutes (17). Such deposits are very porous and must be heat treated to decrease porosity by lateral diffusion and to increase adhesion.…”

Section: Preparation Of Spectroscopically Pure Nickelmentioning

confidence: 99%

The Electrochemistry of Nickel

Wesley¹

1952

Ind. Eng. Chem.

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“…Since there were many recesses in the several pump parts, it was decided to produce the coating by electroless plating (1). This method is distinct from plating due to displacement by the metal on which the nickel is to be deposited, a procedure which was discussed by Piontelli (2) and, more recently, by Wesley and Copson (3).…”

Section: New Fieldsmentioning

confidence: 99%

A Note on the Possible Role of the Solid Surface in Electroless Plating

Glenn¹,

Cook²,

Hackerman³

1949

J. Electrochem. Soc.

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The exhaustion of many high-grade raw materials and the need for using what hitherto has been left in the ground or in the tailings pile has focused attention or, the utility of the electrolytic cell and the electric furnace in the production of high-grade industrial materials from low-grade and complex ores. Electroprocess industries offer a means for meeting the continually increasing demands of manufacturing industry for high-quality materials of controlled specifications.A consideration of those industries termed electrochemical shows them to be "process industries" in which power is of more than normal importance.Stepwise they conform to the concept of "unit operations" and "unit processes" of the chemical engineer; they are chemical engineering industries. The different training and functions of the chemist and the chemical engineer are beginning to be appreciated by the layman. The industrial chemist often manages manufacturing plants; the electrochemist with a purely theoretical background and viewpoint never does. The industrial electrochemist or the electrochemical engineer never can get away from the important power and engineering aspects.

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Coating Steel with Nickel by Immersion in Nickel Chloride Solutions

Cited by 8 publications

References 2 publications

Electroless Metallization of the Elements: Survey and Progress

Electroless Metallization of the Elements: Survey and Progress

The Electrochemistry of Nickel

A Note on the Possible Role of the Solid Surface in Electroless Plating

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