Two connected labelled graphs H 1 and H 2 of nullity one, with identical one-vertex deleted subgraphs H 1 − z 1 and H 2 − z 2 and having a common eigenvector in the nullspace of their 0-1 adjacency matrix, can be overlaid to produce the superimposition Z. The graph Z is H 1 + z 2 and also H 2 + z 1 whereas Z + e is obtained from Z by adding the edge {z 1 , z 2 }. We show that the nullity of Z cannot take all the values allowed by interlacing. We propose to classify graphs with two chosen vertices according to the type of the vertices occurring by using a 3-type-code. Out of the 27 values it can take, only 9 are hypothetically possible for Z, 8 of which are known to exist. Moreover, the SSP molecular model predicts conduction or insulation at the Fermi level of energy for 11 possible types of devices consisting of a molecule and two prescribed connecting atoms over a small bias voltage. All 11 molecular device types are realizable for general molecules, but the structure of Z and of Z + e restricts the number to just 5.