1983
DOI: 10.1007/bf01019497
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Coagulation equations with gelation

Abstract: Smoluchowski's equation for rapid coagulation is used to describe the kinetics of gelation, in which the coagulation kernel Kij models the bonding mechanism. For different classes of kernels we derive criteria for the occurrence of gelation, and obtain critical exponents in the pre-and postgelation stage in terms of the model parameters; we calculate bounds on the time of gelation to, and give an exact postgelation solution for the model K,j = (/j)'~ (~0 > 1/2) and Kq = a i+j

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Cited by 221 publications
(156 citation statements)
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“…One is similar to random percolation models (Herrmann, Stauffer, and Landau 1983;Manneville and de Seze 1981) and uses stochastic simulations on a lattice to evaluate statistics of the evolving system. Another uses differential equations describing the concentrations of polymers of different sizes (Hendriks, Ernst, and Ziff 1983). We employ this second type of model in this work because it is readily adapted to include source and sink terms of polymer and analytic methods can be used to predict gel formation.…”
Section: Gelationmentioning
confidence: 99%
See 1 more Smart Citation
“…One is similar to random percolation models (Herrmann, Stauffer, and Landau 1983;Manneville and de Seze 1981) and uses stochastic simulations on a lattice to evaluate statistics of the evolving system. Another uses differential equations describing the concentrations of polymers of different sizes (Hendriks, Ernst, and Ziff 1983). We employ this second type of model in this work because it is readily adapted to include source and sink terms of polymer and analytic methods can be used to predict gel formation.…”
Section: Gelationmentioning
confidence: 99%
“…In the remainder of this paper, we review an analysis of an existing model of gelation for the case that the total amount of polymers is fixed (Hendriks, Ernst, and Ziff 1983;Ziff and Stell 1980). If polymer is removed from this system, gelation may not occur (Hendriks 1984).…”
mentioning
confidence: 99%
“…is gelling [25,39,53]. Following the contributions [53,88] the conjecture for non-gelling coagulation kernels (1.8) is completely solved in [4] for the discrete coagulation equations (1.1)-(1.2), an alternative proof being given in [46].…”
Section: Introductionmentioning
confidence: 99%
“…A formal calculation in ref. 8 showed that solutions with time-dependent densities do not exist for these kernels (cf. Theorem 3.6 for a rigorous proof of this).…”
Section: Examplesmentioning
confidence: 99%
“…For compact clusters in d dimensions e= 1-d -a, but other values of e are also of interest. (8) The multiplicative form (1.3) might apply to situations in which bond linking was the dominant mechanism. Note that, for the kernel (1.2), the rates for large-large and large-small interactions have the same order of magnitude (i.e., a/,k ~ aj.j for large j and small k), whereas for (1.3), large-large interactions dominate.…”
Section: Introductionmentioning
confidence: 99%