CO2 reduction to formate on an affordable bismuth metal-organic framework based catalyst

Ávila-Bolívar, Beatriz; Cepitis, Ritums; Alam, Mahboob; Assafrei, Jürgen-Martin; Ping, Kefeng; Aruväli, Jaan; Kikas, Arvo; Kisand, Vambola; Vlassov, Sergei; Käärik, Maike; Leis, Jaan; Ivaništštev, Vladislav; Starkov, Pavel; Montiel, Vicente; Solla-Gullón, José; Kongi, Nadežda

doi:10.1016/j.jcou.2022.101937

Cited by 17 publications

(12 citation statements)

References 51 publications

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“…Ávila‐Bolívar et al reported the preparation of a simple, tunable Bi‐based electrocatalyst using MOF as an affordable precursor (Figure 20b ). [ 207 ] The carbon‐rich ligand within this MOF is 1H‐benzo[d]imidazole‐5,6‐diol, combined with bismuth chloride. In theoretical studies, the enhanced eCO 2 RR to formate is linked to metallic Bi sites.…”

Section: Advanced Electrocatalysts For Cathodic Reactionsmentioning

confidence: 99%

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Electro‐Synthesis of Organic Compounds with Heterogeneous Catalysis

et al. 2022

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Electro-organic synthesis has attracted a lot of attention in pharmaceutical science, medicinal chemistry, and future industrial applications in energy storage and conversion. To date, there has not been a detailed review on electro-organic synthesis with the strategy of heterogeneous catalysis. In this review, the most recent advances in synthesizing value-added chemicals by heterogeneous catalysis are summarized. An overview of electrocatalytic oxidation and reduction processes as well as paired electrocatalysis is provided, and the anodic oxidation of alcohols (monohydric and polyhydric), aldehydes, and amines are discussed. This review also provides in-depth insight into the cathodic reduction of carboxylates, carbon dioxide, C=C, C≡C, and reductive coupling reactions. Moreover, the electrocatalytic paired electro-synthesis methods, including parallel paired, sequential divergent paired, and convergent paired electrolysis, are summarized. Additionally, the strategies developed to achieve high electrosynthesis efficiency and the associated challenges are also addressed. It is believed that electro-organic synthesis is a promising direction of organic electrochemistry, offering numerous opportunities to develop new organic reaction methods.

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Section: Advanced Electrocatalysts For Cathodic Reactionsmentioning

confidence: 99%

Section: Advanced Electrocatalysts For Cathodic Reactionsmentioning

confidence: 99%

Electro‐Synthesis of Organic Compounds with Heterogeneous Catalysis

et al. 2022

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“…Numerous two-dimensional materials, including MOFs, 4,23 COFs, 6 exfoliated WS 2 , 24 MoS 2 and g-C 3 N 4 , 25 and graphene, 26 demonstrate photocatalytic behaviour under specific circumstances. Graphene and reduced graphene oxide (rGO), the most acceptable two-dimensional nanosheet structures, show a huge capacity for different applications including transistors, optoelectronics, drug delivery, hydrogen production, CO 2 reduction, energy storage devices, sensors, lubrication, catalysis, etc.…”

Section: Introductionmentioning

confidence: 99%

“…DFT calculations can also help to evaluate the difference in the concentration of charge carriers at the band edge levels after introducing vacancy defects, which can further scrutinise the transition probability of photoinduced electrons and holes. 23,26,37…”

Section: Introductionmentioning

confidence: 99%

“…DFT calculations can also help to evaluate the difference in the concentration of charge carriers at the band edge levels after introducing vacancy defects, which This journal is © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2023 can further scrutinise the transition probability of photoinduced electrons and holes. 23,26,37 In this synthesis process, 2 g of Bi(NO 3 ) 3 Á5H 2 O and 0.6 g of thioacetamide (TAA) are separately mixed with 25 ml of ethylene glycol under continuous stirring conditions for 30 min. After that, both solutions are mixed, and the pH of the mixture is adjusted to 8 using 3 M NaOH solution.…”

Section: Introductionmentioning

confidence: 99%

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Selective photo-reduction of CO₂ to methanol using Cu-doped 1D-Bi₂S₃/rGO nanocomposites under visible light irradiation

et al. 2023

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Promises of MOF‐Based and MOF‐Derived Materials for Electrocatalytic CO₂ Reduction

Mamaghani,

Liu,

Zhang

et al. 2024

Advanced Energy Materials

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Electrocatalytic CO2 reduction (ECR) powered by renewable electricity is a promising technology to mitigate carbon emissions and lessen the dependence on fossil fuels toward a carbon‐neutral energy cycle. Metal–organic frameworks (MOFs) and their derivatives, due to their excellent intrinsic activity, have emerged as promising materials for the ECR to high‐demand products. However, challenges such as unsatisfactory energy efficiency, selectivity, and relatively low production rates hinder their industrial scalability. Here, a comprehensive and critical review is presented that summarizes the state‐of‐the‐art progress in MOF‐based and MOF‐derived CO2 electroreduction catalysts from design and functionality perspectives. The fundamentals of CO2 reduction reaction (CO2RR) over heterogeneous catalysts, reaction mechanisms, and key challenges faced by ECR are described first to establish a solid foundation for forthcoming in‐depth analyses. MOF's building blocks, properties, and shortcomings pertinent to ECR including low conductivity and stability, are systematically discussed. Moreover, comprehensive discussions are provided on MOF‐based and MOF‐derived catalysts design, fabrication, characterization, and CO2RR activity to pinpoint the intricate structure‐property‐performance relationship. Finally, promising recommendations are put forward for enhancing MOF electrocatalysts activity, selectivity, and durability. This work may serve as a guideline for developing high‐performance MOF‐related catalysts for CO2RR, benefiting researchers working in this growing and potentially game‐changing area.

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CO2 reduction to formate on an affordable bismuth metal-organic framework based catalyst

Cited by 17 publications

References 51 publications

Electro‐Synthesis of Organic Compounds with Heterogeneous Catalysis

Electro‐Synthesis of Organic Compounds with Heterogeneous Catalysis

Selective photo-reduction of CO₂ to methanol using Cu-doped 1D-Bi₂S₃/rGO nanocomposites under visible light irradiation

Promises of MOF‐Based and MOF‐Derived Materials for Electrocatalytic CO₂ Reduction

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CO2 reduction to formate on an affordable bismuth metal-organic framework based catalyst

Cited by 17 publications

References 51 publications

Electro‐Synthesis of Organic Compounds with Heterogeneous Catalysis

Electro‐Synthesis of Organic Compounds with Heterogeneous Catalysis

Selective photo-reduction of CO2 to methanol using Cu-doped 1D-Bi2S3/rGO nanocomposites under visible light irradiation

Promises of MOF‐Based and MOF‐Derived Materials for Electrocatalytic CO2 Reduction

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Product

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Selective photo-reduction of CO₂ to methanol using Cu-doped 1D-Bi₂S₃/rGO nanocomposites under visible light irradiation

Promises of MOF‐Based and MOF‐Derived Materials for Electrocatalytic CO₂ Reduction