1987
DOI: 10.1007/bf02069212
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CO2 hydrogenation on iron-containing mono- and bimetallic catalysts

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“…The spectrum displays multiple bands between 1050 and 3010 cm −1 . The different species found at the surface of the catalyst during reaction include: La2O2CO3 (1050 cm −1 ) [46], unidentate formates on the Ni surface (1305 and 1607 cm −1 ) [47], formates on the La2O3 surface (1350 and 1500 cm −1 ) [40], bidentate formates on the γ-Al2O3 support (1375, 1395, 1590, and 3010 cm −1 ) [47], adsorbed CO on Ni in bridge configuration (1860 and 1910 cm −1 ) [47,48], adsorbed CO on Ni in linear configuration (2030 cm −1 ) [47,48], and adsorbed/gaseous CO2 (2320 and 2360 cm −1 ). Conversion of CO2 into CH4 during reaction was corroborated by the presence of the characteristic multi-peak bands observed at ca.…”
Section: Reaction Routesmentioning
confidence: 99%
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“…The spectrum displays multiple bands between 1050 and 3010 cm −1 . The different species found at the surface of the catalyst during reaction include: La2O2CO3 (1050 cm −1 ) [46], unidentate formates on the Ni surface (1305 and 1607 cm −1 ) [47], formates on the La2O3 surface (1350 and 1500 cm −1 ) [40], bidentate formates on the γ-Al2O3 support (1375, 1395, 1590, and 3010 cm −1 ) [47], adsorbed CO on Ni in bridge configuration (1860 and 1910 cm −1 ) [47,48], adsorbed CO on Ni in linear configuration (2030 cm −1 ) [47,48], and adsorbed/gaseous CO2 (2320 and 2360 cm −1 ). Conversion of CO2 into CH4 during reaction was corroborated by the presence of the characteristic multi-peak bands observed at ca.…”
Section: Reaction Routesmentioning
confidence: 99%
“…An example of in-situ DRIFTS analysis profile for the La-Ni/γ-Al 2 O 3 catalyst immediately following a H 2 pulse is provided in Figure 6a [47,48], and adsorbed/gaseous CO 2 (2320 and 2360 cm −1 ). Conversion of CO 2 into CH 4 during reaction was corroborated by the presence of the characteristic multi-peak bands observed at ca.…”
Section: Reaction Routesmentioning
confidence: 99%