“…1–4 In this situation, reversible solid oxide cells (RSOCs) have emerged owing to favourable thermodynamics and kinetics of CO 2 conversion at high temperatures and reversible operational modes on the same device. 5–8 RSOC construction is generally composed of three sections: the air electrode which is exposed to the air-occurring for oxygen evolution reaction (OER) or the oxygen reduction reaction (ORR), the electrolyte, an oxygen ion conduction medium with almost no electronic conductivity, separating the air electrode and fuel electrode, and the fuel electrode where the crucial CO 2 /CO redox reactions take place. 9–12 It is well known that CO 2 molecules have a strong CO chemical bond, 13–15 which increases the difficulty of electrolyzing CO 2 , resulting in that the RSOC performance is mainly determined by the fuel electrode.…”