CO2 capture materials: a review of current trends and future challenges

Dziejarski, Bartosz; Serafin, Jarosław; Andersson, Klas; Krzyżyńska, Renata

doi:10.1016/j.mtsust.2023.100483

Cited by 27 publications

(18 citation statements)

References 662 publications

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“…The exact mechanisms of carbon dioxide adsorption in activated biocarbons can vary depending on the specific type of activated biocarbon and the conditions of the adsorption process. Factors such as PSD, surface chemistry, and temperature can all affect the adsorption behavior of carbon dioxide in activated biocarbons. , …”

Section: Resultsmentioning

confidence: 99%

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Functional Activated Biocarbons Based on Biomass Waste for CO₂ Capture and Heavy Metal Sorption

Serafin,

Kishibayev,

Tokpayev

et al. 2023

ACS Omega

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Inexpensive porous activated biocarbons were prepared from biomass and agriculture waste following the method of thermal and hydrothermal carbonization and activation with superheated water vapor. The activated biocarbons were characterized by nitrogen adsorption–desorption at 77 K, SEM, XRD, Raman spectrometry, FTIR spectroscopy, determination of particle size, and elemental composition by XRF. The specific surface area was in the range of 240–709 m 2 /g, and the total pore volume was from 0.12 to 0.43 cm 3 /g. The percentage of microporosity in activated biocarbons was 89–92%. These activated biocarbons have been used for CO 2 and heavy metal sorption. Activated biocarbons based on pine cones and birch prepared by thermal carbonization and activation with superheated water vapor had the highest ability to capture CO 2 and amounted to 6.43 and 6.00 mmol/g at 273 K, as well as 4.57 and 4.22 mmol/g at 298 K, respectively. The best activated biocarbon was characterized by unchanged stability after 30 adsorption and desorption cycles. It was proved that the adsorption of CO 2 depends on narrow micropores (<1 nm). Activated biocarbons have also been analyzed as effective adsorbents for removing Cu 2+ , Zn 2+ , Fe 2+ , Ni 2+ , Co 2+ , and Pb 2+ ions from aqueous solutions. Activated biocarbons are effective adsorbents for the removal of lead and zinc ions from aqueous solutions.

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Section: Resultsmentioning

confidence: 99%

“…Factors such as PSD, surface chemistry, and temperature can all affect the adsorption behavior of carbon dioxide in activated biocarbons. 74,75 Figure 8 shows the results of carbon dioxide sorption at 273 and 298 K and a pressure of 1 bar with activated biocarbons based on plant waste.…”

Section: Study Of Ph and Determination Of Isotherms Of Heavy Metal Ad...mentioning

confidence: 99%

Functional Activated Biocarbons Based on Biomass Waste for CO₂ Capture and Heavy Metal Sorption

Serafin,

Kishibayev,

Tokpayev

et al. 2023

ACS Omega

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“…In continuation, with respect to ADCS, it offers various advantages, like it can be easily driven by low-grade energy sources like waste heat, solar, or exhaust coming out of the automobile and multiple industries; thus, suitable for stationary and mobile applications. − Various adsorbents can be employed in ADCS or any other sorption-based systems, like MOFs, zeolites, and activated carbons (ACs) out of which ACs are preferred because they offer several advantages over other adsorbents, viz less cost, easy and cheap synthesis, insensitivity toward moisture, good thermal stability, higher CO 2 adsorption affinity, faster kinetics, higher surface area, better pore size distribution, tunable pore structure, low energy requirements for regeneration, and excellent chemical stability and resistance toward both acidic and alkaline environments. − There are many precursors from which ACs can be developed, out of which biomass or waste biomass resources can be a potential precursor as it enables an environmentally friendly approach, and most importantly, the biomass precursors are readily available in abundance and cheap.…”

Section: Introductionmentioning

confidence: 99%

Experimental Investigation and Thermodynamic Analysis of Coconut-Shell-Derived Activated Carbon for CO₂-Based Advanced Adsorption Cooling Systems

Gautam,

Chaudhary,

Singh

et al. 2024

Ind. Eng. Chem. Res.

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The current investigation explores the CO 2 adsorption capacity of an indigenous coconut-shell-derived activated carbon, namely AC CARB 6X12 55, at an adsorption temperature and pressure of 5−70 °C and 0−42 bar, respectively, suitable for CO 2 -based adsorption cooling applications using an in-house developed high-pressure test facility. Additionally, experiments are conducted to measure thermal diffusivity, thermal conductivity, and specific heat of activated carbon using the hot-disk method on a TPS 2500 S analyzer. The activated carbon possesses the maximum CO 2 adsorption capacity of 0.70 kg/kg at 5 °C and 32 bar. Isotherm modeling is carried out based on experimental data employing Toth, D−A, and modified D−A isotherm models, followed by detailed thermodynamic investigation to estimate the heat of adsorption, adsorbed phase-specific heat, enthalpy, and entropy. Based on the adsorption isotherm data and thermophysical properties, study is extended to explore the performance of different advanced CO 2 -based adsorption cooling systems employing internal heat and mass recovery schemes, an ejector expansion, and a thermoelectric subcooler. The results confirm that the suggested cycle modifications are crucial for cooling applications, as a maximum COP and SCE of 0.341 and 44.88 kJ/kg, respectively, with an increment of 163% in system COP compared to the basic cycle, are achieved.

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“…Global warming mainly caused by the excessive CO 2 gas emission has seriously threatened our survival. − Thus, the development of carbon capture and sequestration (CCS) technologies is of high interest. , Among them, discovering highly efficient and less-energy-consumed CO 2 capture materials is greatly important. , Current and popular used carbon capture technology is the aqueous amine solutions as chemisorption media, which generally meets problems of the high energy inputs and corrosion of pipelines. , Recently, the alternative processes in relation to physisorption by solid porous adsorbents have been intensively investigated. , In these almost three decades, as a new type of porous materials, metal–organic frameworks (MOFs) become focuses for carbon capture due to their diversified structures, high porosity, tunable pore sizes, and adjustable pore surface properties, etc. − …”

Section: Introductionmentioning

confidence: 99%

Finely Tuning Metal Ion Valences of [Fe_3–xM_x(μ₃–OH)(Carboxyl)₆(pyridyl)₂] Cluster-Based ant-MOFs for Highly Improved CO₂ Capture Performances

Wang,

Cheng,

Bai

2024

ACS Appl. Mater. Interfaces

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Solvothermal reactions of different trinuclear precursors and 5-(pyridin-4-yl)isophthalic acid (H 2 L) successfully led to four anionic ant topological MOFs as Fe 3−x M x (μ 3 −OH)(CH 3 COO) 2 (L) 2 •(DMA + )•DMF [M = Mn(II), Fe(II), Co(II), x = 0, 1, 2 and 3], namely, NJTU-Bai79 [NJTU-Bai = Nanjing Tech University Bai's group, Mn 3 (μ 3 −OH)], NJTU-Bai80 [Fe 2 Mn(μ 3 −OH)], NJTU-Bai81 [Fe 3 (μ 3 −OH)], and NJTU-Bai82 [Fe 2 Co(μ 3 −OH)], which possess the narrow pores (2.5−6.0 Å). NJTU-Bai80−82 is able to be tuned to the neutral derivatives [NJTU-Bai80−82(-ox), ox = oxidized] with M 2+ ions oxidized to M 3+ ones in the air and the OH − ions coordinated on M 3+ ions. Very interestingly, selective CO 2 /N 2 adsorptions of NJTU-Bai80−82(-ox) are significantly enhanced with the CO 2 adsorption uptakes more than about 6 times that of NJTU-Bai79. GCMC simulations further revealed that neutral NJTU-Bai80−82(-ox) supplies more open frameworks around the −CH 3 groups at separate spaces to the CO 2 gas molecules with relatively more pores available to them after the removal of counterions. For the first time, finely tuning metal ion valences of metal clusters of ionic MOFs and making them from electrostatic to neutral were adopted for greatly improving their CO 2 capture properties, and it would provide another promising strategy for the exploration of high-performance CO 2 capture materials.

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CO2 capture materials: a review of current trends and future challenges

Cited by 27 publications

References 662 publications

Functional Activated Biocarbons Based on Biomass Waste for CO₂ Capture and Heavy Metal Sorption

Functional Activated Biocarbons Based on Biomass Waste for CO₂ Capture and Heavy Metal Sorption

Experimental Investigation and Thermodynamic Analysis of Coconut-Shell-Derived Activated Carbon for CO₂-Based Advanced Adsorption Cooling Systems

Finely Tuning Metal Ion Valences of [Fe_3–xM_x(μ₃–OH)(Carboxyl)₆(pyridyl)₂] Cluster-Based ant-MOFs for Highly Improved CO₂ Capture Performances

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CO2 capture materials: a review of current trends and future challenges

Cited by 27 publications

References 662 publications

Functional Activated Biocarbons Based on Biomass Waste for CO2 Capture and Heavy Metal Sorption

Functional Activated Biocarbons Based on Biomass Waste for CO2 Capture and Heavy Metal Sorption

Experimental Investigation and Thermodynamic Analysis of Coconut-Shell-Derived Activated Carbon for CO2-Based Advanced Adsorption Cooling Systems

Finely Tuning Metal Ion Valences of [Fe3–xMx(μ3–OH)(Carboxyl)6(pyridyl)2] Cluster-Based ant-MOFs for Highly Improved CO2 Capture Performances

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Product

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Functional Activated Biocarbons Based on Biomass Waste for CO₂ Capture and Heavy Metal Sorption

Functional Activated Biocarbons Based on Biomass Waste for CO₂ Capture and Heavy Metal Sorption

Experimental Investigation and Thermodynamic Analysis of Coconut-Shell-Derived Activated Carbon for CO₂-Based Advanced Adsorption Cooling Systems

Finely Tuning Metal Ion Valences of [Fe_3–xM_x(μ₃–OH)(Carboxyl)₆(pyridyl)₂] Cluster-Based ant-MOFs for Highly Improved CO₂ Capture Performances