“…These differences reflect certainly a difference in accessibility of xanthine oxidase-generated free radicals to β-carotene. Without PLA, only the extremity of the β-carotene molecule is accessible whereas, in the case of PLA encapsulation, although the cleavage bond in C7-8 remains major, the favoured cleavage bond determined from molecular modeling calculation in vacuum and from experimental results increases (Bosser & Belin, 1994;Ly, Cao-Hoang, Belin, & Waché, 2008;Waché, Bosser De Ratuld, Ly, & Belin, 2002;Waché, Bosser-DeRatuld, & Belin, 2006;Waché, Bosser-DeRatuld, Lhuguenot, & Belin, 2003).…”