2002
DOI: 10.1016/s1381-1177(02)00167-4
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Co-oxidation of β-carotene in biphasic media

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Cited by 11 publications
(10 citation statements)
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“…These differences reflect certainly a difference in accessibility of xanthine oxidase-generated free radicals to β-carotene. Without PLA, only the extremity of the β-carotene molecule is accessible whereas, in the case of PLA encapsulation, although the cleavage bond in C7-8 remains major, the favoured cleavage bond determined from molecular modeling calculation in vacuum and from experimental results increases (Bosser & Belin, 1994;Ly, Cao-Hoang, Belin, & Waché, 2008;Waché, Bosser De Ratuld, Ly, & Belin, 2002;Waché, Bosser-DeRatuld, & Belin, 2006;Waché, Bosser-DeRatuld, Lhuguenot, & Belin, 2003).…”
Section: Apparition Of Cleavage Productsmentioning
confidence: 97%
“…These differences reflect certainly a difference in accessibility of xanthine oxidase-generated free radicals to β-carotene. Without PLA, only the extremity of the β-carotene molecule is accessible whereas, in the case of PLA encapsulation, although the cleavage bond in C7-8 remains major, the favoured cleavage bond determined from molecular modeling calculation in vacuum and from experimental results increases (Bosser & Belin, 1994;Ly, Cao-Hoang, Belin, & Waché, 2008;Waché, Bosser De Ratuld, Ly, & Belin, 2002;Waché, Bosser-DeRatuld, & Belin, 2006;Waché, Bosser-DeRatuld, Lhuguenot, & Belin, 2003).…”
Section: Apparition Of Cleavage Productsmentioning
confidence: 97%
“…In fact, bcarotene's bleaching was observed when it was solubilized in the aqueous phase with Tween 80 suggesting its reaction with free radicals (Waché, Bosser-DeRatuld, Ly, & Belin, 2002). The high rate of degradation of polar carotenoids (norbixin, bixin, lutein) was also associated with their antioxidant activity in azo-initiated sunflower o/w emulsions .…”
Section: Oxidative Loss Of Carotenoidsmentioning
confidence: 98%
“…Na presença de solventes, a degradação de β-caroteno ocorreu em hexano ou em benzeno. Solventes mais polares como diclorometano ou benzeno inibiram a atividade enzimática 21 . A β-damascenona pode ser formada pela hidrólise de metabólitos secundários complexos derivados de carotenóides, como a neoxantina.…”
Section: Oxidação E Hidrólise Enzimáticaunclassified