Co(II) and Ni(II) bis(salamo)-based tetraoxime complexes: Syntheses, structural characterizations, fluorescence properties, and Hirshfeld analyses

Study for the hydrogen evolution reaction of doped carbon paste composite electrodes with multinuclear Ag(I) complexes based on nitrogen heterocyclic ligand

“…Transition metal complexes have been widely used in the eld of HER due to their novel structure and excellent catalytic performance, and have achieved good results. [23][24][25][26][27]. Recent years, Lin Hongyan et al synthesized a 2D Cu complex using 1,4-bis(5-(3-pyridyl)tetrazolyl)-butane as a ligand and obtained a low η 10 of 59.4 mV and a Tafel slope of 74 mV•dec − 1 by HER studies [28].…”

Against the Norm: Non Irving–Williams Transmetalation in Transition Metal Dimers

“…A large proportion of complexes found in the literature have ligand frameworks derived from salen type Schiff bases, as not only do they have simple preparations but they also commonly have preformed multidentate coordination pockets, providing a driving force for the coordination and formation of a stable complex. , One of the downfalls of Schiff base ligands, however, is the ease at which they undergo cleavage in acidic conditions. This is where o -alkyldiamines and bis-oximes have become popular as these structures, an extension to Schiff bases, are found to have greater stability toward acidic conditions. − …”