To
further reduce the toxicity of heavy metals (HMs) in sewage
sludge (SS), organic acid (oxalic acid, citric acid, acetic acid)
washing was used before co-hydrothermal carbonization (co-HTC) with
pinewood. The results showed the total concentrations of six HMs (As,
Cu, Ni, Cr, Mn, and Zn) in hydrochar produced at 230 °C decreased
obviously during co-HTC. More importantly, F1 + F2 fractions of Ni,
Cr, Mn, and Zn were also lowered. With the pretreatment of citric
acid, the hydrochar from co-HTC exhibited the lowest potential ecological
risk among all simples. Compared with the hydrochar produced from
SS, the coalification degree, higher heating values (5.61–6.19
MJ/kg), and combustion behavior of the hydrochar derived from co-HTC
were upgraded and improved. These findings offered a viable technology
that could lower the bioavailability of HMs and realize the energy
value of SS.