CO 2 , CH 4 and N 2 separation with a 3DFD-printed ZSM-5 monolith

Couck, Sarah; Lefevere, Jasper; Mullens, Steven; Protasova, LN Lidia; Meynen, Vera; Desmet, Gert; Baron, Gino V.; Denayer, Joeri

doi:10.1016/j.cej.2016.09.046

Cited by 133 publications

(103 citation statements)

References 32 publications

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“…Currently, printing methods are not limited to utilising inks comprised of plastics for art exhibitions and may also employ inks comprised of ceramics, metals, graphene additives, and even stimuli-responsive hydrogel composites [129] for prototyping and industrial applications [130][131][132]. Recently scaffolds [133], membranes [134][135][136], carbons [137], zeolites [138][139][140], aminosilicate adsorbents [141], and heterogeneous catalytic systems [142] by taking advantage of this technique.…”

Section: D Printing Methodsmentioning

confidence: 99%

Hierarchical Metal–Organic Frameworks with Macroporosity: Synthesis, Achievements, and Challenges

et al. 2019

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HIGHLIGHTS• The advantages of macroporous metal-organic frameworks (MOFs) in comparison with micro-and mesoporous MOFs are discussed.• A range of synthetic methods for the fabrication and characterisation of hierarchical MOFs with macroporosity are reviewed.• The applications, advancements, and challenges of each method are compared and assessed in detail.ABSTRACT Introduction of multiple pore size regimes into metalorganic frameworks (MOFs) to form hierarchical porous structures can lead to improved performance of the material in various applications.In many cases, where interactions with bulky molecules are involved, enlarging the pore size of typically microporous MOF adsorbents or MOF catalysts is crucial for enhancing both mass transfer and molecular accessibility. In this review, we examine the range of synthetic strategies which have been reported thus far to prepare hierarchical MOFs or MOF composites with added macroporosity. These fabrication techniques can be either pre-or post-synthetic and include using hard or soft structural template agents, defect formation, routes involving supercritical CO 2 , and 3D printing. We also discuss potential applications and some of the challenges involved with current techniques, which must be addressed if any of these approaches are to be taken forward for industrial applications.

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Section: D Printing Methodsmentioning

confidence: 99%

Hierarchical Metal–Organic Frameworks with Macroporosity: Synthesis, Achievements, and Challenges

et al. 2019

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“…[8][9][10] However, adsorption with porous solids has advantages, such as friendliness to the environment and long operational lifetime. 5,11 Therefore, there have been various porous materials designed as adsorbents for use in CO 2 capture, such as zeolites, 12,13 mesoporous silicas, 14,15 metal organic frameworks, [16][17][18] and activated carbons. 19,20 Zeolites, a class of crystals with regular hole wall, such as ZSM-5, 13X, b, and 5A, have been widely used in industrial applications due to their excellent adsorption capacities at low CO 2 partial pressure and high reusability in regeneration.…”

Section: Introductionmentioning

confidence: 99%

Adsorption of carbon dioxide by a novel amine impregnated ZSM-5/KIT-6 composite

Lin

Wei

et al. 2017

RSC Adv.

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“…[49] However, so far neither ceramic composites nor preceramic polymers have been used for direct 3D printing of highresolution ceramic flow-through reactors. [53] [50] Here, preceramic polymers with adjustable rheological properties could in future work become an interesting alternative for direct patterning of high-resolution components for chemical synthesis applications.…”

Section: Ceramicsmentioning

confidence: 99%

High‐Performance Materials for 3D Printing in Chemical Synthesis Applications

et al. 2019

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3D printing has emerged as an enabling technology for miniaturization. High‐precision printing techniques such as stereolithography are capable of printing microreactors and lab‐on‐a‐chip devices for efficient parallelization of biological and biochemical reactions under reduced uptake of reactants. In the world of chemistry, however, up until now, miniaturization has played a minor role. The chemical and thermal stability of regular 3D printing resins is insufficient for sustaining the harsh conditions of chemical reactions. Novel material formulations that produce highly stable 3D‐printed chips are highly sought for bringing chemistry up‐to‐date on the development of miniaturization. In this work, a brief review of recent developments in highly stable materials for 3D printing is given. This work focuses on three highly stable 3D‐printable material systems: transparent silicate glasses, ceramics, and fluorinated polymers. It is further demonstrated that 3D printing is also a versatile technique for surface structuring of polymers to enhance their wetting performance. Such micro/nanostructuring is key to selectively wetting surface patterns that are versatile for chemical arrays and droplet synthesis.

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CO 2 , CH 4 and N 2 separation with a 3DFD-printed ZSM-5 monolith

Cited by 133 publications

References 32 publications

Hierarchical Metal–Organic Frameworks with Macroporosity: Synthesis, Achievements, and Challenges

Hierarchical Metal–Organic Frameworks with Macroporosity: Synthesis, Achievements, and Challenges

Adsorption of carbon dioxide by a novel amine impregnated ZSM-5/KIT-6 composite

High‐Performance Materials for 3D Printing in Chemical Synthesis Applications

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