Clustering Six Electrons within “Dawson‐Like” Polyoxometalate: An Open Route toward Its Post‐functionalization
Gabrielle Mpacko Priso,
Mohamed Haouas,
Nathalie Leclerc
et al.
Abstract:Super‐reduction of polyoxometalates (POMs) in solution is of fundamental interest for designing innovative energy storage systems. In this article, we show that the “Dawson‐like” POM can undergo a disproportionation process during its massive electron uptake, leading to species containing three metal‐metal bonds as evidenced by X‐ray diffraction, multi‐nuclear magnetic resonance spectroscopy (1H and 183W NMR), extended X‐ray absorption fine structure (EXAFS), UV/Vis, and voltammetry techniques. This result ind… Show more
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