2009
DOI: 10.1016/j.jhazmat.2009.01.039
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Cloud point extraction for the spectrophotometric determination of phosphorus(V) in water samples

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Cited by 25 publications
(8 citation statements)
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“…Despite the great progress made in the development of modern microextraction techniques, only a few related studies focused on phosphate determination were found in the literature, namely cloud point extraction of phosphomolybdenum blue using the nonionic surfactant Triton X-114 [22], extraction of the ion pair formed between 12-molybdophosphate and malachite green into a methyl isobutyl ketone followed by microvolume spectrophotometry [23], directly suspended droplet microextraction combined with energy-dispersive X-ray fluorescence spectrometry [24], and dispersive micro-solid phase extraction of ortho-phosphate ions onto magnetite nanoparticles followed by determination as its molybdenum blue complex [25] (Table 3). When compared with existing solvent microextraction techniques (Table 3), the suggested method has a comparable linear range and a comparable or better detection limit, does not require sophisticated, expensive or special equipment neither complicated procedure, enables the use of a larger volume of sample, and uses a solvent less soluble in water.…”
Section: Resultsmentioning
confidence: 99%
“…Despite the great progress made in the development of modern microextraction techniques, only a few related studies focused on phosphate determination were found in the literature, namely cloud point extraction of phosphomolybdenum blue using the nonionic surfactant Triton X-114 [22], extraction of the ion pair formed between 12-molybdophosphate and malachite green into a methyl isobutyl ketone followed by microvolume spectrophotometry [23], directly suspended droplet microextraction combined with energy-dispersive X-ray fluorescence spectrometry [24], and dispersive micro-solid phase extraction of ortho-phosphate ions onto magnetite nanoparticles followed by determination as its molybdenum blue complex [25] (Table 3). When compared with existing solvent microextraction techniques (Table 3), the suggested method has a comparable linear range and a comparable or better detection limit, does not require sophisticated, expensive or special equipment neither complicated procedure, enables the use of a larger volume of sample, and uses a solvent less soluble in water.…”
Section: Resultsmentioning
confidence: 99%
“…This type of extraction by the cloud point method was initially described by Watanabe and Tanaka for the preconcentration of Zn(II) using 1-(2-pyridylazo)napthol (PAN) as a ligand and PONPE as an extractant. Recently, cloud point technique has been successfully employed for the purification, determination and preconcentration of different species of biological interest (Afkhami & Noroozi-Asl, 2009;Sume, Narin, Soylak, Yuruk, & Dgan, 2007), organic compounds such as phenols, polycyclic aromatic hydrocarbons and polychlorinated compound (Pan, Wang, Zu, Wu, & Qi, 2010;Purkait, DasGupta, & De, 2006), radionuclide (Pepper, Peterman, Tranter, & White, 2009) and dyes Pourreza & Elhami, 2007).…”
Section: Introductionmentioning
confidence: 99%
“…This reaction has been proposed based on the phosphate's reaction with molybdate to form phosphomolybdenum blue in acidic medium and its application to water samples through cloud point extraction [15]. The reaction has been explored to develop a simple and sensitive spectrophotometric method to measure arsenic at nanogram level concentrations.…”
Section: Resultsmentioning
confidence: 99%