Abstract:In this work, the CLOPPA approach is extended to allow the bond‐contribution analysis of the anisotropic part, ΔJ, of the indirect nuclear spin‐spin coupling tensor, J. As an example this method is applied to study the role played by the X‐Y bond, its antibonding orbital, and the Y lone pairs in determining the Fermi contact‐spin dipolar cross contribution to Δ1J(XY) in compounds of type Me3X(SINGLE BOND)Y (X = C, Si, Sn, Pb; Y = F, Cl). That contribution is found to be the main one, except for X = Pb, in this… Show more
ABSTRACT:The potential of NMR spin-spin coupling constants as probes to study fine details of electronic molecular structures is briefly discussed in this work through two different examples. A qualitative analysis of the polarization propagator expression for the Fermi contact term is applied for predicting factors affecting 1 J CH , and comments are made about how to generalize those results to different types of onebond spin-spin couplings. Moreover, the Natural J Coupling method is applied to get insight into electronic factors defining a Karplus relationship of type 3 J HH (180°) Ͻ 3 J HH (0°) known in the literature for some amino acids.
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