This case study focuses on twelve compacted clay soil samples to understand their fundamental physical and thermal properties. For each sample, the density, thermal conductivity, thermal diffusivity, specific heat, and drying shrinkage were assessed. The identification and characterisation of the materials were also carried out by positioning them into the ternary diagram based on the percentage of sand, silt, and clay. These properties are definitive for the performance characteristics of materials used in rammed earth wall construction. The aim is to provide information for better knowledge and prediction regarding the dynamic heat flow in rammed earth walls. Experimental results show a relatively wide range of values for each property, reflecting the diverse properties of the sampled clays. The thermophysical characteristics of the 12 types of earth analysed showed correlations with reports in the literature in terms of density (1490–2150 kg/m3), porosity (23.22–39.99%), specific heat capacity (701–999 J/kgK), and thermal conductivity (0.523–1.209 W/mK), which indicates them as materials suitable for use in the construction of rammed earth walls. Using test data, a dynamic assessment of heat flow through simulated rammed earth walls was performed. For a better understanding of the results obtained, they were compared with results obtained for simulations where the building element would be made of concrete, i.e., a mineral wool core composite. Thus, heat flux at the wall surface and mass flux, respectively, during the 16 years of operation showed similar evolution for all 12 types of clay material analysed, with small variations explained by differences in thermophysical characteristics specific to each type of S1–S12 earth. In the case of walls made from clay material, there is a stabilisation in the evolution of the water content phenomenon by the 5th year of simulation. This contrasts with walls made of concrete, where the characteristic water content appears to evolve continuously over the 16-year period. Therefore, it can be said that in the case of the construction elements of existing buildings, which have already gone through a sufficient period for the maturation of the materials in their construction elements, the rammed earth wall quickly develops a moisture buffer function. In the case of simulating a mineral wool core composite wall, it cannot perform as a temperature or humidity buffer, exhibiting an enthalpy exchange with indoor air that is only 4% of that of the rammed earth walls; consequently, it does not play a significant role in regulating indoor comfort conditions. Overall, there is confirmation of the temperature and moisture buffering capabilities of rammed earth walls during both warm and cold periods of the year, which is consistent with other reports in the literature. The findings of this research provide a better insight into clay as a material for rammed earth walls for more efficient design and construction, offering potential improvements regarding indoor comfort, energy efficiency, and sustainability. The data also provides useful information in the fields of architecture and civil engineering regarding the use of clay as an eco-friendly building material. The results emphasise the importance of thoroughly understanding the thermophysical properties of clay to ensure the efficiency of rammed earth construction.
