Abstract. The Yangtze River is
the longest river in China; nearly one-third of the national population lives
along the river. Air quality over the Yangtze River is important as it may
have significant influences on the aquatic ecosystem, the health of everyone
living along the Yangtze River, and regional climate change. Chemical
compositions of ambient aerosol were determined during a comprehensive cruise
campaign carried out along the mid–lower reaches of the Yangtze River (MLYR)
in winter of 2015. The total average concentration of PM2.5 was 119.29±33.67 µg m−3, and the dominant ionic composition in
PM2.5 was SO42- with an average concentration of 15.21±6.69 µg m−3, followed by NO3- (13.76±4.99 µg m−3), NH4+ (9.38±4.35 µg m−3), and Ca2+ (2.23±1.24 µg m−3) in this cruise. Based on the filter samples,
the concentration and chemical composition of PM2.5 were remarkably
varied or fluctuated from coastal areas to inland over the MLYR region.
Crustal elements (Ca, Mg, Al, and K) from floating dust showed peak
concentrations in the Yangtze River Delta (YRD) region, while secondary
inorganic species (SO42-, NO3-, and
NH4+) and some of the most enriched elements (Pb, As, Se, and
Cd) presented high levels in central China (Wuhan region). The significant
correlation between Se and SO42- suggested that coal combustion
may play an important role in secondary inorganic aerosol formation. The
relatively high enrichment factors (EFs) of Ca (EFs >100) suggested the
crustal elements may derive from anthropogenic sources. Furthermore, the
concentration of levoglucosan in PM2.5 and the CO column level from
satellite observation were greatly enhanced in the rural areas (Anhui and
Jiangxi), indicating that biomass burning may make a remarkable contribution
to rural areas. The concentrations of typical tracer for heavy oil (V and Ni)
significantly increased in the Shanghai port, which was mainly ascribed to
ship emissions, based on the air mass source analysis and the relatively high
ratio of V ∕ Ni as well. The results shown herein portray a good picture
of air pollution along the Yangtze River.