1982
DOI: 10.1016/s0020-1693(00)81889-7
|View full text |Cite
|
Sign up to set email alerts
|

Cleavage reactions of alkylcobaloximes with anhydrous hydrogen chloride

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
2

Citation Types

0
2
0

Year Published

1983
1983
2001
2001

Publication Types

Select...
3
2
1

Relationship

0
6

Authors

Journals

citations
Cited by 8 publications
(2 citation statements)
references
References 26 publications
0
2
0
Order By: Relevance
“…The macrocyclic ligand in cobaloximes is an almost perfectly planar structure carrying a formal double negative charge. The hydrogen bonding between the two monoanionic covalent halves of the equatorial ligand is sufficient to confer considerable structural rigidity and chemical stability. The complexes are able to withstand strong acids , and even Grignard reagents . In deuterium oxide solutions, replacement of the bridging hydrogen atom with deuterium is slow even in the presence of bases or acids. , This stability allows the catalysts to be employed in aqueous systems as well as organic media…”
Section: Catalystsmentioning
confidence: 99%
See 1 more Smart Citation
“…The macrocyclic ligand in cobaloximes is an almost perfectly planar structure carrying a formal double negative charge. The hydrogen bonding between the two monoanionic covalent halves of the equatorial ligand is sufficient to confer considerable structural rigidity and chemical stability. The complexes are able to withstand strong acids , and even Grignard reagents . In deuterium oxide solutions, replacement of the bridging hydrogen atom with deuterium is slow even in the presence of bases or acids. , This stability allows the catalysts to be employed in aqueous systems as well as organic media…”
Section: Catalystsmentioning
confidence: 99%
“…The hydrogen bonding between the two monoanionic covalent halves of the equatorial ligand is sufficient to confer considerable structural rigidity and chemical stability. [85][86][87][88] The complexes are able to withstand strong acids 89,90 and even Grignard reagents. 91 In deuterium oxide solutions, replacement of the bridging hydrogen atom with deuterium is slow even in the presence of bases or acids.…”
Section: Catalyst Screeningmentioning
confidence: 99%