Cleavage reactions of alkylcobaloximes with anhydrous hydrogen chloride

Fergusson, Stuart B.; Baird, Michael C.

doi:10.1016/s0020-1693(00)81889-7

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2001

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Cited by 8 publications

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“…The macrocyclic ligand in cobaloximes is an almost perfectly planar structure carrying a formal double negative charge. The hydrogen bonding between the two monoanionic covalent halves of the equatorial ligand is sufficient to confer considerable structural rigidity and chemical stability. − The complexes are able to withstand strong acids , and even Grignard reagents . In deuterium oxide solutions, replacement of the bridging hydrogen atom with deuterium is slow even in the presence of bases or acids. , This stability allows the catalysts to be employed in aqueous systems as well as organic media…”

Section: Catalystsmentioning

confidence: 99%

“…The hydrogen bonding between the two monoanionic covalent halves of the equatorial ligand is sufficient to confer considerable structural rigidity and chemical stability. [85][86][87][88] The complexes are able to withstand strong acids 89,90 and even Grignard reagents. 91 In deuterium oxide solutions, replacement of the bridging hydrogen atom with deuterium is slow even in the presence of bases or acids.…”

Section: Catalyst Screeningmentioning

confidence: 99%

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