Cleavage of the dimeric heterometallic complexes [Pd(dppf)(μ-Cl)]2[BArF24]2 (dppf = 1,1′-bis(diphenylphosphino)ferrocene, BArF24 = tetrakis(bis-3,5-trifluoromethylphenyl)borate) via addition of monodentate phosphine ligands

Wolfarth, Sadie A.; Colicchio, Nick G.; Nataro, Cassie S.; Reinheimer, Eric W.; Nataro, Chip

doi:10.1016/j.poly.2022.115915

Polyhedron

2022

DOI: 10.1016/j.poly.2022.115915

|View full text |Cite

Cleavage of the dimeric heterometallic complexes [Pd(dppf)(μ-Cl)]2[BArF24]2 (dppf = 1,1′-bis(diphenylphosphino)ferrocene, BArF24 = tetrakis(bis-3,5-trifluoromethylphenyl)borate) via addition of monodentate phosphine ligands

Sadie A. Wolfarth

Nick G. Colicchio

Cassie S. Nataro

et al.

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2024

Publication Types

Select...

Article1

Relationship

Self Cite0

Independent1

Authors

Journals

Cited by 1 publication

References 64 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

Cleavage of [Pd2(PP)2(μ-Cl)2][BArF24]2 (PP = Bis(phosphino)ferrocene, BArF24 = Tetrakis(3,5-bis(trifluoromethyl)phenyl)borate) with Monodentate Phosphines

Leiby,

Parparcén,

Ding

et al. 2024

Molecules

View full text Add to dashboard Cite

The addition of Na[BArF24] (BArF24 = tetrakis(3,5-bis(trifluoromethyl)phenyl)borate) to [Pd(PP)Cl2] (PP = 1,1′-bis(phosphino)ferrocene ligands) compounds results in the loss of a chloride ligand and the formation of the dimeric species [Pd2(PP)2(μ-Cl)2][BArF24]2. In most cases, the addition of a monodentate phosphine, PR3, to these dimeric species leads to cleaving of the dimer and formation of [Pd(PP)(PR3)Cl][BArF24]. While these reactions are readily observed via a significant color change, the 31P{1H} NMR spectra offer more significant support, as the singlet for the dimer is replaced with three doublets of doublets. The reaction seems to take place for a wide range of PR3 ligands, although there do appear to be steric limitations to the reaction. The compounds were thoroughly characterized by NMR, and X-ray crystal structures of several of the compounds were obtained. In addition, the ferrocenyl backbone of the 1,1′-bis(phosphino)ferrocene ligands provides an opportunity to examine the oxidative electrochemistry of these compounds. In general, the potential at which oxidations of these compounds occurs shows a dependence on the phosphine substituents.

show abstract

Cleavage of [Pd2(PP)2(μ-Cl)2][BArF24]2 (PP = Bis(phosphino)ferrocene, BArF24 = Tetrakis(3,5-bis(trifluoromethyl)phenyl)borate) with Monodentate Phosphines

Leiby,

Parparcén,

Ding

et al. 2024

Molecules

View full text Add to dashboard Cite

show abstract

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

customersupport@researchsolutions.com

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Cleavage of the dimeric heterometallic complexes [Pd(dppf)(μ-Cl)]2[BArF24]2 (dppf = 1,1′-bis(diphenylphosphino)ferrocene, BArF24 = tetrakis(bis-3,5-trifluoromethylphenyl)borate) via addition of monodentate phosphine ligands

Cited by 1 publication

References 64 publications

Cleavage of [Pd2(PP)2(μ-Cl)2][BArF24]2 (PP = Bis(phosphino)ferrocene, BArF24 = Tetrakis(3,5-bis(trifluoromethyl)phenyl)borate) with Monodentate Phosphines

Cleavage of [Pd2(PP)2(μ-Cl)2][BArF24]2 (PP = Bis(phosphino)ferrocene, BArF24 = Tetrakis(3,5-bis(trifluoromethyl)phenyl)borate) with Monodentate Phosphines

Contact Info

Product

Resources

About