Clean and Efficient Synthesis Using Mechanochemistry: Coordination Polymers, Metal-Organic Frameworks and Metallodrugs

Friščić, Tomislav; Halász, Ivan; Štrukil, Vjekoslav; Eckert‐Maksić, Mirjana; Dinnebiér, Robert E.

doi:10.5562/cca2014

Cited by 75 publications

(27 citation statements)

References 62 publications

(79 reference statements)

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“…In order to minimize these risks solvent free techniques are being developed, with mechanochemical M A N U S C R I P T A C C E P T E D ACCEPTED MANUSCRIPT synthesis specifically attracting increased attention in the field [68][69][70].…”

Section: Mechanochemical Synthesismentioning

confidence: 99%

Effect of the structural constituents of metal organic frameworks on carbon dioxide capture

Andirova

Cogswell

et al. 2016

Microporous and Mesoporous Materials

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Section: Mechanochemical Synthesismentioning

confidence: 99%

Effect of the structural constituents of metal organic frameworks on carbon dioxide capture

Andirova

Cogswell

et al. 2016

Microporous and Mesoporous Materials

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“…The second issue can be addressed by the concept of mechanochemistry. Mechanochemistry has been applied repeatedly as a sustainable and cost‐effective alternative to conventional synthesis concepts in the fields of pharmaceutical, organic, and inorganic chemistry, especially in the field of metal–organic frameworks (MOFs) . Mechanochemical syntheses rely on the input of mechanical energy to initiate chemical reactions, for instance by grinding solids in high‐energy ball mills.…”

Section: Introductionmentioning

confidence: 99%

Nitrogen‐Doped Biomass‐Derived Carbon Formed by Mechanochemical Synthesis for Lithium–Sulfur Batteries

et al. 2018

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Nitrogen‐doped carbons were synthesized by a solvent‐free mechanochemically induced one‐pot synthesis by using renewable biomass waste. Three solid materials are used: sawdust as a carbon source, urea and/or melamine as a nitrogen source, and potassium carbonate as an activation agent. The resulting nitrogen‐doped porous carbons offer a very high specific surface area of up to 3000 m2 g−1 and a large pore volume up to 2 cm3 g−1. Also, a high nitrogen content of 4 wt % (urea only) up to 12 wt % (melamine only) is generated, depending on the nitrogen and carbon sources. The mechanochemical reaction and the impact of different wood components on the porosity and surface functionalities are investigated by nitrogen physisorption and high‐resolution X‐ray photoelectron spectroscopy (XPS). These N‐doped carbons are highly suitable as cathode materials for Li–S batteries, showing high initial discharge capacities of up to 1300 mAh gsulfur−1 (95 % coulombic efficiency) and >75 % capacity retention within the first 50 cycles at low electrolyte volume.

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“…8,36,[290][291][292][293][294][295][296] In recent years, mechanochemistry (i.e. [299][300][301][302][303] The present section focuses on the applications of various solvent-free protocols in implementing carbon-carbon bond forming reactions reported in recent times. 297,298 Mechanochemical synthesis affords many advantages, such as greater efficiency with regard to time, materials, and energy usage, as well as the discovery of new or improved reactivity and products, as an alternative approach to synthesis.…”

Section: Carbon-carbon Bond Forming Reactions In Solvent-free/neat Comentioning

confidence: 99%

Design for carbon–carbon bond forming reactions under ambient conditions

Brahmachari

2016

RSC Adv.

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Carbon-carbon (C-C) bond forms the 'backbone' of nearly every organic molecule, and lies at the heart of the chemical sciences! This transformation has always been one of the most useful and fundamental reactions in the development of organic chemistry. Currently, the concept of 'green chemistry' is globally acclaimed and has already advanced quite significantly to come out as a distinct branch of chemical sciences. Among the principles of 'green chemistry', one principle is dedicated to "design of energy efficiency" -that is to develop synthetic strategies that require less/minimum amount of energy to carry out a specific reaction with optimum productivity. And the most effective way-out to save energy is to develop strategies/protocols that are capable enough to carry out the transformations at ambient temperature and pressure! As part of on-going developments on green synthetic strategies, designing for reactions under ambient conditions coupled with other green aspects is, thus, an area of current choice. This review is aimed to offer an up-to-date development on the design of carbon-carbon bond forming protocols to access a wide variety of organic molecules of topical significance under ambient conditions. The account highlights on the brilliant applications of reaction conditions such as the use of solvents or no solvent, catalysts or no catalyst, and the use of green tools like ball-milling, ultrasonication and visible light in achieving the goal! Design for Carbon Carbon Frameworks at Ambient ConditionsN Me Me Me O O COOH Br Br (Graphic for TOC)

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Clean and Efficient Synthesis Using Mechanochemistry: Coordination Polymers, Metal-Organic Frameworks and Metallodrugs

Cited by 75 publications

References 62 publications

Effect of the structural constituents of metal organic frameworks on carbon dioxide capture

Effect of the structural constituents of metal organic frameworks on carbon dioxide capture

Nitrogen‐Doped Biomass‐Derived Carbon Formed by Mechanochemical Synthesis for Lithium–Sulfur Batteries

Design for carbon–carbon bond forming reactions under ambient conditions

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