Abstract:Clay has a low environmental impact and can develop into many different products. The research presents two different case studies. In the first, the clay is the binder of raw earth doughs in order to produce clay-bricks. We investigate the effects of natural fibrous reinforcements (rice straws and basalt fibers) in four different mixtures. From the comparison with a mix without reinforcements, it is possible to affirm that the 0.40% of basalt fibers reduce the shrinkage by about 25% and increase the compressi… Show more
“…The microstructural investigations show that the pressed sample has a composite-like structure with a kaolinite matrix and the filler role is fulfilled by quartz and mullite particles. Such a mineral base is reported in the literature for various sustainable materials such as plasters [43,44] or pozzolan structures for geopolymer production [45,46]. Our microstructural observation evidenced that pressing the slurry with a humidity of around 30% facilitates the kaolinite binder activity, increasing the material cohesion.…”
Ceramic slurry wastes have a significant hazardous potential when dumped. Their recycling as raw material is a sustainable approach for the development of nature-friendly applications. The microstructure and mechanical properties play a key role in the success of this sustainable recycling. Ceramic slurry samples resulting from the wall and floor tiles production facility were analyzed. The mineral composition was investigated by XRD combined with mineralogical microscopy and the microstructure was investigated by SEM microscopy coupled with EDX spectroscopy and elemental mapping. The ceramic slurry contains: quartz, kaolinite, mullite and small amounts of lepidocrocite. Quartz and mullite particles have sizes in the range of 5–100 μm and kaolinite has small particles of around 1 to 30 μm. Iron hydroxide crystallized as lepidocrocite is finely distributed among kaolinite aggregates. It makes the slurry unable to be reused in the technological process because of the glaze staining risk, but it does not affect the material cohesion. Thus, the cylindrical samples were prepared at progressive compactions rates as follows: 1808.55; 1853.46; 1930.79 and 2181.24 kg/m3 and dried. Thereafter, were subjected to a compression test with a lower compression strength of 0.75 MPa for lower density and a higher strength of 1.36 MPa for the higher density. Thus, slurry compaction enhances the kaolinite binding ability. The Young’s Modulus slightly decreases with the compaction increasing due to local microstructure rigidizing. This proves the binding ability of kaolinite, which properly embeds quartz and mullite particles into a coherent and resistant structure. The fractography analysis reveals that fracture starts on the internal pores at low compaction rates and throughout the kaolinite layer in the samples with high compactness. The observed properties indicate that the investigated ceramic slurry is proper as a clay-based binder for sustainable ecological buildings, avoiding the exploitation of new clay quarries. Also, it might be utilized for ecological brick production.
“…The microstructural investigations show that the pressed sample has a composite-like structure with a kaolinite matrix and the filler role is fulfilled by quartz and mullite particles. Such a mineral base is reported in the literature for various sustainable materials such as plasters [43,44] or pozzolan structures for geopolymer production [45,46]. Our microstructural observation evidenced that pressing the slurry with a humidity of around 30% facilitates the kaolinite binder activity, increasing the material cohesion.…”
Ceramic slurry wastes have a significant hazardous potential when dumped. Their recycling as raw material is a sustainable approach for the development of nature-friendly applications. The microstructure and mechanical properties play a key role in the success of this sustainable recycling. Ceramic slurry samples resulting from the wall and floor tiles production facility were analyzed. The mineral composition was investigated by XRD combined with mineralogical microscopy and the microstructure was investigated by SEM microscopy coupled with EDX spectroscopy and elemental mapping. The ceramic slurry contains: quartz, kaolinite, mullite and small amounts of lepidocrocite. Quartz and mullite particles have sizes in the range of 5–100 μm and kaolinite has small particles of around 1 to 30 μm. Iron hydroxide crystallized as lepidocrocite is finely distributed among kaolinite aggregates. It makes the slurry unable to be reused in the technological process because of the glaze staining risk, but it does not affect the material cohesion. Thus, the cylindrical samples were prepared at progressive compactions rates as follows: 1808.55; 1853.46; 1930.79 and 2181.24 kg/m3 and dried. Thereafter, were subjected to a compression test with a lower compression strength of 0.75 MPa for lower density and a higher strength of 1.36 MPa for the higher density. Thus, slurry compaction enhances the kaolinite binding ability. The Young’s Modulus slightly decreases with the compaction increasing due to local microstructure rigidizing. This proves the binding ability of kaolinite, which properly embeds quartz and mullite particles into a coherent and resistant structure. The fractography analysis reveals that fracture starts on the internal pores at low compaction rates and throughout the kaolinite layer in the samples with high compactness. The observed properties indicate that the investigated ceramic slurry is proper as a clay-based binder for sustainable ecological buildings, avoiding the exploitation of new clay quarries. Also, it might be utilized for ecological brick production.
“…In the last few years, sustainability issues have gained momentum in the construction industry [9,10], with particular attention on the materials used [9,11,12]. From the point of view of recycling policies and environmental sustainability initiatives, inorganic polymers can play a relevant role, enabling the reuse of wastes in a wide range of potential applications [11,[13][14][15][16].…”
This paper analyses the net social benefits deriving from the medium-scale production of geopolymers based on volcanic ash compared to traditional cementitious materials used in construction and restoration sectors. In contrast to the existing literature grounded on the physical and mechanical characterization of geopolymers, our analysis considers two aspects: public finance savings from avoiding the disposal of volcanic ash in landfills and environmental benefits deriving from reduction in CO2 releases due to the production process at room temperature. Our case study focuses on the reuse of natural waste, namely the volcanic ash of the Mt. Etna volcano (Italy), whose disposal involves significant costs for society. Its use in the alkaline activation process avoids the exploitation of natural resources. Considering the huge amount of volcanic ash from Mt. Etna that falls on the urban areas of Eastern Sicily, the results show relevant economic benefits, in terms of both avoided costs and tax reductions for the citizens. Alongside these, significant environmental benefits are evidenced thanks to the release of up to 78% lower CO2 emissions by synthesised materials with volcanic ash than by traditional cementitious ones. Overall, the social cost savings compared to traditional materials is 0.339 EUR/kg for geopolymer.
“…La Noce et al highlight the increasing energy demands and consequent resource depletion, pointing out that interventions in the built environment are crucial for addressing these issues. Current evaluation methods primarily assess buildings based on their operational energy consumption and emissions, underscoring the need for comprehensive approaches encompassing construction materials' environmental impacts throughout their lifecycle [5]. However, a building operates as an open system, involved in an ongoing flow of energy, materials, and social and economic connections with its environment, extending beyond its period of use.…”
This chapter examines integrating innovative clay materials within modern architecture’s environmental stewardship framework. Focusing on clay, it emphasizes its role in sustainable design and construction, driven by escalating ecological concerns and the need for green development. The chapter highlights clay’s enduring appeal, resilience, energy efficiency, and eco-friendliness in architecture. It traces clay’s historical use, from traditional bricks and terracotta to advanced composites, and examines significant advancements in production techniques that enhance material properties while reducing environmental impact. Sustainable clay extraction practices, lifecycle analysis, thermal efficiency, and clay’s role in healthier indoor environments are discussed. Case studies illustrate contemporary architects’ use of clay to meet esthetic, structural, and environmental needs, addressing barriers such as structural, economic, and regulatory challenges. Recommendations for modifying regulations, enhancing education, and embracing technological innovation are provided to promote clay’s broader use in construction. The chapter concludes that clay should be significant in future architectural design and construction, driven by innovative and ecologically responsible approaches. It argues that strategic use of clay, combined with technology and ecological ethics, can achieve sustainable development goals and create environmentally responsible, efficient, and esthetically appealing built environments.
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