Citric Acid as Multidentate Flexible Ligand for Multinuclear Late‐3 d‐Metal Complexes and Single‐Molecule Magnets
Masanori Wakizaka,
Masahiro Yamashita
Abstract:Citric acid (citH4) is a ubiquitous product in nature with an interesting chemistry owing to its three carboxy and one hydroxy groups, which can be deprotonated in a stepwise manner into six kinds of citrate anions involving two protonation isomers. Deprotonated citrates easily coordinate to late‐3d‐metal ions (Mn, Fe, Co, Ni, Cu, and Zn), affording complexes including mono‐, di‐, tri‐, tetra‐, hexa‐, hepta‐, octa‐, nona‐, and 21‐nuclear complexes with a variety of structures. Magnetic interactions between met… Show more
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