Chromogenic Calixarenes

Menon, Shobhana K.; Gidwani, M. S.; Agrawal, Y. K.

doi:10.1515/revac.2003.22.1.35

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Structural Modifications1

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2007

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“…Hence the phenolic hydroxyl groups at the lower rim of the calixarenes represent an excellent reactive function for the introduction of groups, which modify the shape, and the complexing properties of these molecules. Preliminary work on the lower rim of calixarenes has been started with alkylation and acylation reactions, which have been reviewed extensively in books [1, 9, 10] and review articles [5–8]. Different lower-rim modifications can be done as follows.…”

Section: Structural Modificationsmentioning

confidence: 99%

Lower-Rim Substituted Calixarenes and Their Applications

Jose

Menon

2007

Bioinorganic Chemistry and Applications

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This review discusses in detail “calixarenes” since their discovery as by-products of the phenol formaldehyde bakelites till the present scenario wherein calixarene has assumed a new dimension in the field of supramolecular chemistry. Extensive literature exists for calixarenes; but herein we have tried to concentrate on the different lower-rim modified calixarenes with their potential applications. An attempt has also been made to critically evaluate the synthesis procedures for different lower-rim substituted calixarenes.

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