Chlorobis(1,10-phenanthroline)(trichloroacetato)manganese(II)

Abstract

Key indicatorsSingle-crystal X-ray study T = 298 K Mean (C-C) = 0.003 Å Disorder in main residue R factor = 0.030 wR factor = 0.084 Data-to-parameter ratio = 18.7For details of how these key indicators were automatically derived from the article, see

Dichloridobis[(S)-2-hydroxypropionamide-κ2O,O′]manganese(II)

“…The Mn-Cl bond distances [2.4535 (7) and 2.4786 (7) Å] are in good agreement with those found in similar octahedral Mn II complexes like e.g. in [chloridobis(1,10phenanthroline)(trichloroacetato)manganese(II)] [2.4374 (2) Å](Chen et al, 2006). Among the two possible coordination modes (N,O or O,O) in metal complexes with lactamide or its derivatives described in the literature, the title compound presents the O,O mode as in the before cited [Zn(lactamide) 3 ] 2+ and [B(lactamide) 2 ] + complexes.…”

“…For related literature, see: Bekaert et al (2005Bekaert et al ( , 2007; Chen et al (2006); Girma et al (2005). Table 1 Hydrogen-bond geometry (Å , ).…”

Chlorido(chlorodifluoroacetato-κO)bis(1,10-phenanthroline-κ2N,N′)manganese(II)

“…For isostructural chlorido(1,10-phenanthroline)(trichloroacetato)manganese(II), see: Chen et al (2006).…”