Chlorine Oxyfluorides

Schack, Carl J.

doi:10.1016/s0065-2792(08)60033-3

Cited by 46 publications

(22 citation statements)

References 183 publications

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“…They generally exhibit amphoteric character and can form complexes with strong Lewis acids and bases [1]. The central halogen atom in the compounds has an oxidation state ranging from +I to +VII and a coordination number from 1 to 8 [2,3], exceeding that allowed by the traditional theory of Lewis and Langmuir [4][5][6][7].…”

Section: Introductionmentioning

confidence: 99%

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A theoretical prediction of thermodynamic properties of chlorine fluorides

Du¹,

Liu²,

Wang³

et al. 2011

Thermochimica Acta

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Section: Introductionmentioning

confidence: 99%

“…The ionic structures were also found for the adducts of ClF 3 This type of substances can be used in explosive industry since they react with organic materials spontaneously and exothermically [24][25][26][27]. To understand their reactivities, it is necessary to study their thermodynamic properties, e.g.…”

Section: Introductionmentioning

confidence: 99%

A theoretical prediction of thermodynamic properties of chlorine fluorides

Du¹,

Liu²,

Wang³

et al. 2011

Thermochimica Acta

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“…The vibrational and rotational CF (Gv(t) and GR(t), respectively) were found using two procedures: lz (1) Fourier transform of the Raman band contours found experimentally (the discrete Fourier transform); (2). The vibrational and rotational CF (Gv(t) and GR(t), respectively) were found using two procedures: lz (1) Fourier transform of the Raman band contours found experimentally (the discrete Fourier transform); (2).…”

Section: Resultsmentioning

confidence: 54%

“…2 The bond lengths and bond angles assumed previously z for C1OF 3 (without experimental structural data) correspond to a regular C, structure of the XYZ 3 type (trigonal bipyramid). 2 The bond lengths and bond angles assumed previously z for C1OF 3 (without experimental structural data) correspond to a regular C, structure of the XYZ 3 type (trigonal bipyramid).…”

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confidence: 99%

“…ClOF 3 + BFm --~ =" [ClOF4I-[BFm_ll +, (2) where AF n and BF m are Lewis acid and base, respectively, in a solution in anhydrous HF. 7 It has been noted 8,9 that the acid-base properties of amphoteric halogen fluorides can be revealed by comparing the structural stability of the initial molecule with that of the corresponding ion, which can be done using the data of vibrational spectroscopy.…”

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Raman spectra and structural features of ClOF2 + cation in a solution of anhydrous HF

et al. 1998

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The Raman spectra of CIOF! § cation in solutions of anhydrous HF were studied. In the CIOF2+HF2 -and CIOF2+BF4---HF systems, this cation exists as a pyramidal structure (C s symmetry.), while in the C1OF2+AuF6---HF system, it exists as a planar structure (C2v symmetry). Based on nonempirical calculations by the Hartree--Fock--Roothaan method, an explanation for the dependence of the structure of the C1OF2 + cation on the nature of the anion was proposed. For the C1--O bond vibrations, the correlation functions of vibrational and rotational relaxations were calculated, and the characteristic times of these processes were determined. The main contribution to the formation of the band contours corresponding to the above-mentioned modes is made by the vibrational dephasing.

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Fluorine: Inorganic ChemistryBased in part on the article Fluorine: Inorganic Chemistry by Darryl D. DesMarteau, Charles W. Bauknight, Jr., & Todd E. Mlsna which appeared in theEncyclopedia of Inorganic Chemistry, First Edition.

Atwood

2005

Encyclopedia of Inorganic Chemistry

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This article provides an overview of the extensive and diverse inorganic chemistry of fluorine. Key topics are covered, such as the methods used for the formation of element–fluorine bonds with hydrogen fluoride and elemental fluorine. The article includes a general description of the structure and bonding of common fluorine compounds and the various spectroscopic techniques for their characterization. More specific details are provided for the fluoride compounds of boron, and the groups 14–17 elements. New topics such as the means by which carbon–fluorine bonds may be broken and the fluorination of carbon‐based materials such as fullerenes and nanotubes are included in the appropriate sections.

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Chlorine Oxyfluorides

Cited by 46 publications

References 183 publications

A theoretical prediction of thermodynamic properties of chlorine fluorides

A theoretical prediction of thermodynamic properties of chlorine fluorides

Raman spectra and structural features of ClOF2 + cation in a solution of anhydrous HF

Fluorine: Inorganic ChemistryBased in part on the article Fluorine: Inorganic Chemistry by Darryl D. DesMarteau, Charles W. Bauknight, Jr., & Todd E. Mlsna which appeared in theEncyclopedia of Inorganic Chemistry, First Edition.

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