Chlorination of 1, 1-Dichloroethane

Muraoka, Ryuji; Hani, Hiroshi

doi:10.5059/yukigoseikyokaishi.25.503

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Chlorination In a Complexing Solvent2

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1972

1973

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“…It is well known that the selectivity of photochlorinations in the liquid phase is greatly increased when aromatic compounds [8] or CS, [18,19,20] are used as solvents. This is accompanied by a reduction of the overall reaction rate and often by an increase of the activation energy compared to the reaction in so-called "inert" solvents.…”

Section: Chlorination In a Complexing Solventmentioning

confidence: 99%

Liquid‐phase hydrogen abstraction from chlorinated ethanes by chlorine atoms

Martens

Franklin

Godfroid

et al. 1973

Int J of Chemical Kinetics

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Section: Chlorination In a Complexing Solventmentioning

confidence: 99%

Liquid‐phase hydrogen abstraction from chlorinated ethanes by chlorine atoms

Martens

Franklin

Godfroid

et al. 1973

Int J of Chemical Kinetics

View full text Add to dashboard Cite

show abstract

Section: Chlorination In a Complexing Solventmentioning

confidence: 99%

Liquid phase hydrogen abstraction from asymmetrically chlorinated ethanes by chlorine atoms

Martens

Godfroid

Verbeyst

1972

Bulletin des Soc Chimique

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The ratios of rates constants of hydrogen atom abstraction by a chlorine atom from both sites of asymmetrical chloroethanes were measured in the liquid phase at -13 to 40°C. The following values were obtained: Ethyl chloride (in CC14) 1,l-dichloroethane 1,1,2-trichloroethane The results are compared with recent gas phase data and discussed. Experiments in a complexing solvent (CS,) show an increased selectivity compared to the liquid phase due to both enthalpic and entropic effects. k,,,/kz,r = 10°~21*o.10 exp (86f100/RT) kz,*/k2., = 10°~26*o~10 exp (120f 100/RT) kz,t/kz,s = 10-0.09*0.'0 exp (100f lOO/RT)

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Chlorination of 1, 1-Dichloroethane

Cited by 2 publications

References 0 publications

Liquid‐phase hydrogen abstraction from chlorinated ethanes by chlorine atoms

Liquid‐phase hydrogen abstraction from chlorinated ethanes by chlorine atoms

Liquid phase hydrogen abstraction from asymmetrically chlorinated ethanes by chlorine atoms

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