“…The solutions will be complex, particularly if the effects of time-dependent chloride binding, charge separation and more than one transport process are considered [31,32]. When an electric field is imposed, oxidation and reduction reactions may induce changes affecting the local pressure and electric field [19,33]. If the model is too complex, it may require parameters that are not readily measurable.…”
Section: Modelling Physical Transport Processesmentioning
confidence: 99%
“…Recent innovations in these techniques have included their extension to areas where the current is applied intermittently [33,74], improvements in the assessment criteria [76], and improvements in the anodes used [77]. Developments have also been made in overcoming the problems associated with the use of sacrificial anodes applied to the surface of concrete [78].…”
Section: Repair Of Chloride-contaminated Concretementioning
The corrosion of steel reinforcement in concrete structures induced by chloride ion contamination is a major problem. Deterioration starts with the loss of protection provided by the concrete cover as the result of chloride ingress. This is followed by corrosion initiation and then propagation. Recent advances in models of chloride penetration into concrete, based on mathematical models of the physical transport processes and an analysis of empirical data, have been made. Inhibitive and aggressive properties of solid phases present at the steel which affect corrosion initiation have been identified. Improved methods have been developed to monitor corrosion rates as well as chloride ingress into the concrete cover. An improved understanding of the deterioration processes has led to new developments in repair techniques.Prog. Struct. Engng. Mater. 2000; 2: 448d458
“…The solutions will be complex, particularly if the effects of time-dependent chloride binding, charge separation and more than one transport process are considered [31,32]. When an electric field is imposed, oxidation and reduction reactions may induce changes affecting the local pressure and electric field [19,33]. If the model is too complex, it may require parameters that are not readily measurable.…”
Section: Modelling Physical Transport Processesmentioning
confidence: 99%
“…Recent innovations in these techniques have included their extension to areas where the current is applied intermittently [33,74], improvements in the assessment criteria [76], and improvements in the anodes used [77]. Developments have also been made in overcoming the problems associated with the use of sacrificial anodes applied to the surface of concrete [78].…”
Section: Repair Of Chloride-contaminated Concretementioning
The corrosion of steel reinforcement in concrete structures induced by chloride ion contamination is a major problem. Deterioration starts with the loss of protection provided by the concrete cover as the result of chloride ingress. This is followed by corrosion initiation and then propagation. Recent advances in models of chloride penetration into concrete, based on mathematical models of the physical transport processes and an analysis of empirical data, have been made. Inhibitive and aggressive properties of solid phases present at the steel which affect corrosion initiation have been identified. Improved methods have been developed to monitor corrosion rates as well as chloride ingress into the concrete cover. An improved understanding of the deterioration processes has led to new developments in repair techniques.Prog. Struct. Engng. Mater. 2000; 2: 448d458
“…Considerably lower voltages, preferably less than 30 V, are used in ECE. Not until the beginning of the 1990s, research reports were published on this method [6][7][8][9][10][11][12][13][14][15][16][17][18][19][20][21][22][23][24][25]. So, the electroremediation applied to chloride extraction using impressed current has been used for over 30 years on a relatively large scale with good success [17,[25][26][27], even though some side effects have been detected [28,29].…”
“…There is some evidence [25] that sustained application of a field of this magnitude and direction may fractionally reduce the Clcontent, and increase the OHcontent, of the pore water at the rebar surface compared with the values expected in the absence of migration effects. Figure 7.…”
Section: Protection and Depassivation Behaviormentioning
A set of partially immersed reinforced concrete columns with mature corrosion patterns was used to demonstrate that corrosion macrocell currents provided "cathodic prevention" to parts of the steel assembly that remained passive even though exposed to high chloride (~ 4.7% of the cement weight) concrete. Depassivation of that steel was observed upon macrocell decoupling.
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