Chiral sandwich compounds of ruthenium(II) and (IV): X-ray crystal structure of [Ru{η5-C5H4(neomenthyl)}2I]I3

A new type of organometallic oligomers has been obtained from the reaction of [(C6Me6)2Ru2H3]+ and dithiophenol derivatives. These oligomers are highly ordered because of the steric hindrance around the metal center and the rigidity of the aromatic units. The electrochemical behavior of the monomers and the oligomers has been studied both in reduction and in oxidation modes. The oligomers have been grafted via electrostatic interactions on glass substrates prefunctionalized by self-assembled monolayers (SAMs). The optical properties of the films have also been investigated.

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Chiral sandwich compounds of ruthenium(II) and (IV): X-ray crystal structure of [Ru{η5-C5H4(neomenthyl)}2I]I3

Cited by 5 publications

References 48 publications

Functionalization of one or two methyl groups in the [Cp*2RuBr]+Br− complex in the reaction with bromine

Functionalization of one or two methyl groups in the [Cp*2RuBr]+Br− complex in the reaction with bromine

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Grafting of Organoruthenium Oligomers on Quartz Substrates: Synthesis, Electrochemistry, Optical Properties, and AFM Investigations

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