Chiral P*‐Monodentate Phosphite Ligand for Pd‐Catalyzed Asymmetric Allylation Reactions.

Abstract

Sulfones Sulfones Q 0600Chiral P*-Monodentate Phosphite Ligand for Pd-Catalyzed Asymmetric Allylation Reactions. -A novel monodentate phosphite ligand with stereogenic phosphorous and carbon atoms, which is easily available from (S)-2-phenylaminomethyl pyrrolidine, is an effective chiral catalyst for the asymmetric allylation of propenyl acetate (I). -(GAVRILOV, K. N.; TSAREV*, V. N.; LYUBIMOV, S. E.; SHYRYAEV, A. A.; ZHEGLOV, S. V.; BONDAREV, O. G.; DAVANKOV, V. A.; KABRO, A. A.; MOISEEV, S. K.; KALININ, V. N.; Mendeleev Commun. 2003, 3, 134-136; Nesmeyanov Inst. Organoelem. Compd., Russ. Acad. Sci., Moscow 117813, Russia; Eng.) -M. Paetzel 46-102