2024
DOI: 10.1002/cplu.202400123
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Chiral Heterometallic Cu8Ln4 Complexes with Enantiopure Schiff Base Ligands: Synthesis, Structural, Spectroscopic and Magnetic Studies

Despina Dermitzaki,
Angeliki Panagiotopoulou,
Michael Pissas
et al.

Abstract: The enantiomerically pure Schiff base ligands H2L‐S and H2L‐R yield chiral heterometallic dodecanuclear complexes of the form [Cu8Ln4(OH)8(OMe)4(O2CBut)8(L‐S or L‐R)4(H2O)4] where LnIII = Gd (1S), Tb (2S), Dy (3S, 3R), Ho (4S, 4R), Er (5S) or Y (6S, 6R) and H2L = (S or R)‐2‐{[(1‐hydroxypropan‐2‐yl)imino]methyl}‐6‐methoxyphenol. The complexes are isomorphous and crystallize in the non‐centrosymmetric polar space group C2 in enantiomeric conformation. The chirality of the Schiff base ligands originates from the … Show more

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