Abstract:Intrinsically chiral metal nanoclusters with crystal structure are highly desirable to gain deep insights into chirality origin of chiral nanostructures and understand structure‐and‐property relationship of heterogeneous catalysts in asymmetric catalysis. Although several strategies including the use of chiral ligands and high‐performance liquid chromatography have been routinely employed to gain nanoclusters with inherent chirality, another simple methodology of spontaneous resolution remains largely unexplor… Show more
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