Up-to-date fluid catalytic cracking catalysts for large-tonnage refining processes work under extremely hard conditions and need to have a high stability to the thermal and steam treatment. Therefore, the purpose of this work was to compare the effect of lanthanum and zirconium additives on the porous characteristics and catalytic activity of the microspherical cracking catalysts in fresh and steamed form that were synthesized based on the Ukrainian kaolin. The synthesized initial sample contained 30% Y zeolite that was transferred to the H-form before the modification by lanthanum and zirconium. The modification led to some decrease in BET surface and samples microporosity, which was substantially intensified after steaming. In the case of zirconium, such a decrease was less than for lanthanum. The effect of the catalysts modification on the vibrations of the structural components of the zeolite lattice was investigated by FTIR spectroscopy. The observed shifts of absorbance frequencies of the bond at 1070 cm -1 , which correspond to the asymmetric vibrations of tetrahedra after corresponding modifications, indicated the isomorphic substitution of the aluminum atoms by zirconium ones. The steamed samples with the zirconium content of 6.5% demonstrated the highest conversion of cumene cracking (an increase by 20-30% as compared with the unmodified sample). Therefore, the modification of fluid catalytic cracking catalysts by zirconium affects both on the adsorption and on the catalytic properties of the steamed samples.