1989
DOI: 10.1002/chin.198917028
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ChemInform Abstract: Voltammetric Studies of the Transpassive Dissolution of Mild Steel in Carbonate/Bicarbonate Solutions.

Abstract: ChemInform Abstract For the first time, a transpassive anodic peak preceding oxygen evolution is detected together with the corresponding reduction peak. The formation of an Fe(VI) species is proposed. Based on the voltammetric results, the general electrochemical behavior of mild steel in carbonate/bicarbonate solutions is discussed with special emphasis on the transpassive region.

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“…1, would account for peak I corresponding to the formation of Fe(OH)2. Range1 et al (7,8) and Beck (9) detected an anodic peak preceding oxygen evolution together with the corresponding reduction peak in cyclic voltammetric studies of mild steel in unsdrred carbonate/bicarbonate solutions and iron in concentrated hydroxide solutions. They proposed that this peak was due to the transpassive anodic dissolution of Fe(EI)-oxide layer and hydrolysis to yield ferrate(VD ion, FeO42".…”
Section: Fe(oh)2 + 2e = Fe°+ 2ohmentioning
confidence: 99%
“…1, would account for peak I corresponding to the formation of Fe(OH)2. Range1 et al (7,8) and Beck (9) detected an anodic peak preceding oxygen evolution together with the corresponding reduction peak in cyclic voltammetric studies of mild steel in unsdrred carbonate/bicarbonate solutions and iron in concentrated hydroxide solutions. They proposed that this peak was due to the transpassive anodic dissolution of Fe(EI)-oxide layer and hydrolysis to yield ferrate(VD ion, FeO42".…”
Section: Fe(oh)2 + 2e = Fe°+ 2ohmentioning
confidence: 99%