ChemInform Abstract: VINYL METHYL TELLURIDE

The chemistry of organotellurium compounds has developed very rapidly during the recent decades. Tellurium reagents find uses in various aspects of synthetic organic chemistry. Organometallic complexes with tellurolato or telluroether ligands show potential application in the fabrication of new materials for electronic devices. The present article emphasizes the preparation and structural characterization of some of the main classes of organic tellurium compounds and their organometallic complexes that are deemed of interest for inorganic chemists.

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“…40- 42 Solutions of sodium in liquid ammonia also provide useful media for the reduction of tellurium.…”

Section: Preparationmentioning

confidence: 99%

“…It has also been shown that solid-state 125 Te NMR spectroscopy is a sensitive tool to identify covalent secondary bonding interactions between the cations and anions. 41 Some illustrative examples are shown in Figure 11. 93 respectively, and are close to single-bond lengths.…”

mentioning

confidence: 99%

Tellurium: Organic and Organometallic Compounds

Laitinen

Oilunkaniemi

2005

Encyclopedia of Inorganic Chemistry

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“…Heteroatom Chemistry DOI 10.1002/hc (12) The third possible way involves the alphadeprotonation of divinyl sulfide followed by the rearrangement of the formed carbanion via unsaturated thioaldehyde (Eq. 13).…”

Section: (11)mentioning

confidence: 99%

“…The conditions of generation of etheneselenolate anions [8][9][10] from divinylselenide and ethenetellurolate anions [8] from divinyltelluride have been found. The methods for the high-yield preparation of divinylselenide and divinyltelluride have been devised [4,11,12].…”

Section: Introductionmentioning

confidence: 99%