ChemInform Abstract: VANADIUM(IV) PORPHYRINS. SYNTHESIS AND SPECTROCHEMICAL CHARACTERIZATION OF DIHALOVANADIUM(IV) PORPHYRINS. EXTENDED X‐RAY ABSORPTION FINE STRUCTURAL STUDY OF DIBROMO(2,3,7,8,12,13,17,18‐OCTAETHYLPORPHYRINATO)VANADIUM(IV)
Abstract:Die Behandlung der Oxoporphyrinato‐V(IV)‐Komplexe (I) mit Thionyl‐ oder Oxalylchlo‐ 134 rid bzw. ‐bromid führt zu den Dihalogeno‐V(IV)‐Derivaten (II), die aufgrund ihrer großen Reaktivität bemerkenswerte Vorläufer für niedrig‐wertige V‐porphyrine sind.
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