ChemInform Abstract: Umwandlungen von β‐Nitro‐alkylphosphinoxiden in α‐Carboxy‐alkylphosphinoxide und einige Umsetzungen dieser Verbindungen.

Петров, К. А.; Chauzov, V. A.; Agafonov, S. V.; Lebedeva, N. Yu.

doi:10.1002/chin.198326278

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Olefinic Acceptors Bearing a Nitro Group1

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2005

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“…Petrov and co-workers [77] carried out a variety of Michael additions to the nitroalkenes 155 and 157 (giving 156 and 158, respectively) and studied the possibilities of derivatising some of them (Scheme 35).…”

Section: Olefinic Acceptors Bearing a Nitro Groupmentioning

confidence: 99%

The Phospha‐Michael Addition in Organic Synthesis

et al. 2005

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Phosphorus is essential for many reagents in organic synthesis, for ligands of late-transition metals and for phosphonoand phosphanylamino acids, the latter being important isosteres of amino acids. Similar to the Michaelis-Arbuzov and the Michaelis-Becker reaction the phospha-Michael addition, i. e. the addition of a phosphorus nucleophile to an acceptor-substituted alkene or alkyne, certainly represents one of the most versatile and powerful tools for the formation of P-C bonds since many different electrophiles and P nu-

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Section: Olefinic Acceptors Bearing a Nitro Groupmentioning

confidence: 99%