ChemInform
 1989
DOI: 10.1002/chin.198937252
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ChemInform Abstract: “Umpolung” Using a Phosphorus Group. A Novel Method for the Chemoselective Synthesis of 2‐Acetonyl‐ or 3‐Acetonylmorpholines.

B Cristau
1
,
Marie Fonte
2
,
E. Torreilles
3

Abstract: Michael addition of the (N‐benzyl)aminoethanol (II) to the vinylphosphonium salt (I) gives the tertiary amine (III) which is cyclized, yielding the 2‐acetonylmorpholine (V) after deprotection.

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