ChemInform Abstract: Transition Metal Tetramolybdate Dihydrates MMo₄O₁₃×2H₂O (M: Co, Ni) Having a Novel Pillared Layer Structure.

Abstract

Cobalt I 7200 Transition Metal Tetramolybdate Dihydrates MMo4O13·2H2O (M: Co, Ni) Having a Novel Pillared Layer Structure. -The title compounds (III) crystallize in the triclinic space group P1 with Z = 1 (single crystal XRD). Tetranuclear units of four edge-sharing MoO6 octahedra are connected via corners to ribbons, which are further linked by corner sharing to form molybdenum oxide sheets. These Mo-O sheets are pillared by CoO6 octahedra. -(EDA*, K.; OHSHIRO, Y.; NAGAI, N.; SOTANI, N.; WHITTINGHAM, M. S.; J. Solid State Chem. 182 (2009) 1, 55-59; Dep. Chem., Grad. Sch. Sci., Kobe Univ., Nada, Kobe 657, Japan; Eng.) -Schramke 13-021