Abstract:Transition-Metal-Free Tunable Chemoselective N Functionalization of Indoles with Ynamides. -Two new reaction pathways of ynamides with heterocycles containing a N-unsubstituted pyrrole unit are developed using NaOtBu as the base. Either Z-indolo-etheneamides or indolo-amidines (XI) can be selectively obtained under the same reaction conditions. -(HENTZ, A.; RETAILLEAU, P.; GANDON, V.; CARIOU, K.; DODD*, R. H.; Angew. Chem., Int. Ed. 53 (2014) 32, 8333-8337, http://dx.doi.org/10.1002/anie.201402767 ; Inst. Chim… Show more
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