2010
DOI: 10.1002/chin.199918285
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ChemInform Abstract: The Use of Furan Derivatives in Asymmetric Synthesis and Transformation

Abstract: ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.

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“…We focused our attention on the asymmetric F−C reactions of furans with active aldehydes, namely, glyoxylates, including diastereoselective and enantioselective approaches . The products of this reaction, 2-furanyl-hydroxyacetic acid esters ( I ) (Scheme ), are very interesting building blocks for the synthesis, and after reduction to diols II , these synthons can be transformed under oxidizing conditions to linear ( III ) as well as cyclic products, e.g., dihydropyranones ( IV ) or dihydropyridones ( V ). Such an approach was utilized for the synthesis of multifunctional chain compounds, higher-carbon sugars, aza sugars, and, e.g., in the synthesis of papulacandin D …”
mentioning
confidence: 99%
“…We focused our attention on the asymmetric F−C reactions of furans with active aldehydes, namely, glyoxylates, including diastereoselective and enantioselective approaches . The products of this reaction, 2-furanyl-hydroxyacetic acid esters ( I ) (Scheme ), are very interesting building blocks for the synthesis, and after reduction to diols II , these synthons can be transformed under oxidizing conditions to linear ( III ) as well as cyclic products, e.g., dihydropyranones ( IV ) or dihydropyridones ( V ). Such an approach was utilized for the synthesis of multifunctional chain compounds, higher-carbon sugars, aza sugars, and, e.g., in the synthesis of papulacandin D …”
mentioning
confidence: 99%