ChemInform Abstract: THE THERMAL ISOMERIZATION OF 5-ACETYL-5-METHYLBICYCLO(2.1.0)PENTANE, ENDO-EXO STEREOMUTATION AND CYCLOPROPYL-ALLYLIC REARRANGEMENT OF THE ENDO KETONE ON SEPARATE POTENTIAL ENERGY SURFACES

Grosclaude, Jean-Pierre; Gonzenbach, Hans-Ulrich; Perlberger, Jean-Claude; Schaffner, Kurt

doi:10.1002/chin.197539118

Chemischer Informationsdienst

1975

DOI: 10.1002/chin.197539118

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ChemInform Abstract: THE THERMAL ISOMERIZATION OF 5-ACETYL-5-METHYLBICYCLO(2.1.0)PENTANE, ENDO-EXO STEREOMUTATION AND CYCLOPROPYL-ALLYLIC REARRANGEMENT OF THE ENDO KETONE ON SEPARATE POTENTIAL ENERGY SURFACES

Jean-Pierre Grosclaude¹,

Hans-Ulrich Gonzenbach²,

Jean-Claude Perlberger³

et al.

Abstract: Es wird gezeigt, daß die Umwandlung zum Keton (III) spezifisch über das endo‐Keton (II) erfolgt und daß dieser Prozeß sowie die Isomerisierung des exo‐Ketons (I) zum ende‐Keton (II) kein gemeinsames Intermediärprodukt aufweisen.

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ChemInform Abstract: THE THERMAL ISOMERIZATION OF 5-ACETYL-5-METHYLBICYCLO(2.1.0)PENTANE, ENDO-EXO STEREOMUTATION AND CYCLOPROPYL-ALLYLIC REARRANGEMENT OF THE ENDO KETONE ON SEPARATE POTENTIAL ENERGY SURFACES

Abstract: Es wird gezeigt, daß die Umwandlung zum Keton (III) spezifisch über das endo‐Keton (II) erfolgt und daß dieser Prozeß sowie die Isomerisierung des exo‐Ketons (I) zum ende‐Keton (II) kein gemeinsames Intermediärprodukt aufweisen.

Cited by 0 publications

References 1 publication

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