ChemInform Abstract: THE KINETICS OF AQUATION AND RACEMIZATION OF SOME CIS‐ CHLORO‐, HYDROXO‐, AND AQUABIS(ETHYLENEDIAMINE)(AMINE)COBALT(III) COMPLEXES
Abstract:Aquation rates for cis-CoCl(en)2(A)2+ (A = 3,5-lutidine, imidazole, N-methylimidazole, benzimidazole) have been determined by halide release titration in 1 .O M HNOz at 50-80°C. Kinetic parameters are (in the above order of A) 1O7k29s (sec-I), 7.4, 5.7, 1.3, 9.7; E, (kJ/mole), 103, 101, 130, 112; log PZ (sec-l), 11.89, 11.53, 16.04, 13.58 8, 38.0, 7.7, 1.7; E, = 150, 135, 152, 157; log PZ = 17.49, 16.18, 18.56, 18.87; ASzgsr = +82, +57, +102, +l08. Rates of racemization of the active hydroxo complexes cis-Co… Show more
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