ChemInform Abstract: The Adamantane Rearrangement of syn‐ and anti‐Tricyclo(4.2.1.1.12,5)decane. Part 2. Rearrangements Initiated by Regioselective Formation of Carbocations at C(3) and C(9).
Abstract:ChemInform Abstract Treatment of the exo-alcohol (I) with BF3/Et3SiH (ionic hydrogenation) gives the anti-hydrocarbon (II) as virtually the sole product which is likewise obtained from the endo-alcohol (III) under the same conditions. In addition, (III) is obtained from the alcohols (IVa) or (IVb). On the other hand, the exo/endo alcohols (V) or (VIII) each afford a mixture of the 2-endo-3-endo-(VI) and 2-exo-3-exo-trimethylene-8,9,10-trinorbornanes (VII). Similar results are obtained from the alcohols (IXa) o… Show more
Set email alert for when this publication receives citations?
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.