ChemInform Abstract: THALLIUM IN ORGANIC SYNTHESIS. 58. REGIOSPECIFIC INTERMOLECULAR OXIDATIVE DEHYDRODIMERIZATION OF AROMATIC COMPOUNDS TO BIARYLS USING THALLIUM(III) TRIFLUOROACETATE
Abstract:Behandlung zahlreicher aromatischer Substrate, wie z.B. (I), (III), (V), mit dem Tl‐Titelreagenz Tl(T?)3 unter verschiedenen Bedingungen a)‐c) führt zu glatter, schneller und direkter regiospezifischer oxidativer Dehydrodimerisierung unter Bildung von Biarylen wie (II), (IV) bzw. (VI).
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