Generalized results of the analysis of synthesis reaction of cyclic acetals of 1,3-dioxolane series by condensation of cyclohex-3-ene-1-carbaldehydes with 1,2-propanediol and its 3chloro-, 3-chloroalkoxy derivatives, as well as their epoxidation, bromination, dichlorocarbenylation on C=C bond of cycle and dienophilic activity were presented. The influence of the nature of substituents on relative reactivity of reacting components and efficiency of the prepared products as the ED-20-based active diluent of the polymer composition has been considered.