ChemInform Abstract: SYNTHESIS OF PROSTAGLANDIN‐F2α BY CONJUGATE ADDITION OF A CUPRATE REAGENT TO 3‐TERT‐BUTYLDIMETHYLSILYLOXYTRICYCLO(3.2.0.02,7)HEPTAN‐6‐ONE
Abstract:Über das gespannte Cyclopropylketon (IV), das aus dem Bromhydrin (III) durch Behandlung mit Dimethyl‐tert.‐butylsilylchlorid/Imidazol in Dimethylformamid und anschließende Dehydrobromierung mit Kalium‐tert.‐butylat zugänglich ist, wird das gesuchte Prostaglandin (IX) dargestellt.
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