ChemInform Abstract: SYNTHESIS OF POLYFLUOROALKYL ESTERS OF TRICHLOROMETHYLPHOSPHONIC AND PHOSPHINIC ACIDS

Krutikov, V. I.; Semenova, E. S.; Maslennikov, I. G.; Lavrent'ev, A. N.

doi:10.1002/chin.198404231

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A Oxidation Reactions1

Cf 3 Soj R F = Cf 3 Ch 2 Chf 2 Cf 2 Ch1

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1996

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“…286 Thus, bis(trifluoroethyl) trichloromethylphosphonite is oxidised by oxygen only under UV radiation. 105 Stronger oxidants -N^, 60 Sulfur adds to tris-and bis-(fluoroalkyl) phosphites with much greater difficulty than to the corresponding alkyl phosphites. The reaction takes place only after prolonged heating in dioxane 61 -62 -164 -292 or pyridine.…”

Section: A Oxidation Reactionsmentioning

confidence: 99%

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Fluoroalkoxy-derivatives of trivalent phosphorus: synthesis and reactivity

Миронов¹,

Konovalova²,

Burnaeva³

et al. 1996

Russ. Chem. Rev.

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ContentsI. Introduction 935 II. The influence of fluorine-containing substituents on the properties of the P(III) atom. Photoelectron 935 spectroscopic and electrochemical data III. Synthesis of fluoroalkoxy-derivatives of P(III) 938 IV. Reactions of fluoroalkyl phosphites 948 V. Conclusion 966 Abstract. The review surveys and gives a systematic account of the electronic structures, syntheses, and chemical properties of fluoroalkyl derivatives of trivalent phosphorus (phosphites, thiophosphites, and amidophophites). The methods of preparation and reactivities of fluoroalkyl phosphites are compared with those of unsubstituted phosphites. The bibliography includes 420 references.

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Section: A Oxidation Reactionsmentioning

confidence: 99%

“…The reactions of carbon tetrachloride with fluoroalkyl phosphorites 105 It has been noted that the elimination of CHCI3 in this reaction is promoted by nonpolar solvents and by the absence of steric shielding of the protons of the CH 2 Si fragment in compound 93.…”

Section: Cf 3 Soj R F = Cf 3 Ch 2 Chf 2 Cf 2 Chmentioning

confidence: 99%