ChemInform Abstract: Synthesis of Novel Carbo‐ and Heterocycles. Part 17. Intramolecular 1,3‐Dipolar Cycloaddition Reaction of 3‐endo‐Azidobicyclo(3.3.1)non‐6‐ene. A Facile Route to 5‐Azaprotoadamant‐4‐ene.

Eguchi, Shoji; Suzuki, Toshimichi; Toi, Nao; Sasaki, Tadashi

doi:10.1002/chin.199033070

ChemInform

1990

DOI: 10.1002/chin.199033070

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ChemInform Abstract: Synthesis of Novel Carbo‐ and Heterocycles. Part 17. Intramolecular 1,3‐Dipolar Cycloaddition Reaction of 3‐endo‐Azidobicyclo(3.3.1)non‐6‐ene. A Facile Route to 5‐Azaprotoadamant‐4‐ene.

Shoji Eguchi

Toshimichi Suzuki

Nao Toi

et al.

Abstract: Thermolysis of 3‐endo‐azidobicyclo(3.3.1)non‐6‐ene (I) in toluene and subsequent treatment with methanol yield the azatricyclodecene (II) which is methylated to produce the iminium iodide (IV).

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ChemInform Abstract: Synthesis of Novel Carbo‐ and Heterocycles. Part 17. Intramolecular 1,3‐Dipolar Cycloaddition Reaction of 3‐endo‐Azidobicyclo(3.3.1)non‐6‐ene. A Facile Route to 5‐Azaprotoadamant‐4‐ene.

Abstract: Thermolysis of 3‐endo‐azidobicyclo(3.3.1)non‐6‐ene (I) in toluene and subsequent treatment with methanol yield the azatricyclodecene (II) which is methylated to produce the iminium iodide (IV).

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