ChemInform Abstract: Synthesis of D‐Desosamine and Analogues by Rapid Assembly of 3‐Amino Sugars.

Abstract

Synthesis of D-Desosamine and Analogues by Rapid Assembly of 3-Amino Sugars.-Key step in the synthesis of D-desosamine and analogs (V) is the chromatography--free procedure for the coupling of chiral nitrobutanols (I) with glyoxal to give pure 3-nitro sugars by crystallization. -(ZHANG, Z.; FUKUZAKI, T.; MYERS*, A. G.; Angew. Chem., Int. Ed. 55 (2016) 2, 523-527, http://dx.