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ChemInform Abstract: Synthesis of 5α‐Androstane‐3β,14β,17β‐triol.
Abstract: The biologically interesting title compound (IV) is synthesized starting from the steroid (Ia) which is transformed to (Ib) by reaction with phenylisocyanate.
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1989
1989
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“…acetic acid. The epoxypregnenolone derivative (32) reacts with hydrogen thiocyanate to give the iminooxathiolane (33), which cyclizes to the oxadiazine (34) with ethanolic ammonium hydroxide. 29- 31 The carbethoxyhydrazone (35) likewise undergoes cyclization to the derivative (26).…”
Section: @ -mentioning
confidence: 99%
“…acetic acid. The epoxypregnenolone derivative (32) reacts with hydrogen thiocyanate to give the iminooxathiolane (33), which cyclizes to the oxadiazine (34) with ethanolic ammonium hydroxide. 29- 31 The carbethoxyhydrazone (35) likewise undergoes cyclization to the derivative (26).…”
Section: @ -mentioning
confidence: 99%
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