Chemischer Informationsdienst
 1977
DOI: 10.1002/chin.197712171
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ChemInform Abstract: SYNTHESIS OF 3‐UNSUBSTITUTED 2‐HYDROXY‐4‐OXOALKANOATES

Antoine Meyer1,
M. Flammang2,
Camille‐Georges Wermuth3

Abstract: Alkinylmagnesiumbromide (I) werden an α‐Ketocarbonsäureester‐ (II) zu Alkinylcarbinolen (III) addiert und in Gegenwart von Quecksilber?D‐acetat mit wäßriger Ameisensäure in 2‐Hydroxy‐4‐oxocarbonsäureester (IV) umgewandelt.

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